Material Safety Data Sheet

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MATERIAL SAFETY DATA SHEET
PRODUCT NAME: BCI-6M
DESCRIPTION: Ink Tank
USED WITH MACHINE(S): BJC8200, S 800 (BJ, S830D, S820D, S900,
S9000
MANUFACTURER: Canon Inc.
30-2, Shimomaruko 3-Chome, Ohta-Ku
Tokyo 146, Japan
Phone: 03-3758-2111
DISTRIBUTOR: Canon UK Limited
Woodhatch
Reigate
Surrey
Phone: 01737 220000
DATE PREPARED: 22/12/00
DATE REVISED: 09/04/03
UK MSDS REF: MSDS3178
MATERIAL SAFETY DATA SHEET
Page 1 of 8
Canon Ink Tank BCI-6MProduct Name:
4707A / F47-3241Product Code:
Canon Inc.Company Name:
30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo 146-8501, JapanAddress:
< Ingredient(s) >
Glycerin
Ethylene glycol
Diethylene glycol
Isopropyl alcohol
Quinoline derivative
Triazine derivative
Ammonia derivative
Water
56-81-5 /
200-289-5
107-21-1 /
203-473-3
111-46-6 /
203-872-2
67-63-0 /
200-661-7
Confidential
Confidential
Confidential
7732-18-5 /
231-79-12
5 - 10
2 - 6
2 - 6
1 - 3
1 - 3
1 - 3
5 - 10
60 - 80
None /
Xn /
Xn /
F /
Xi /
Xi /
Xi /
None /
None /
None
R22
R22
R11
R36
R67
R36
R36
R52/53
None
None
Chemical Name /
Generic name
CAS # /
EC #
Weight
%
(as mist)
Total dust
TWA = 15 mg/m3
Respirable fraction
TWA = 5 mg/m3
Not established
Not established
TWA = 400 ppm,
980 mg/m3
Not established
Not established
Not established
Not established
(as mist)
TWA = 10 mg/m3
(aerosol)
Ceiling =
100 mg/m3
Not established
TWA = 200 ppm,
492 mg/m3
STEL = 400 ppm,
984 mg/m3
Not established
Not established
Not established
Not established
USA
OSHA PEL
ACGIH TLV
Not established
TWA = 20 ppm,
52 mg/m3
STEL = 40 ppm,
104 mg/m3
Not established
Not established
Not established
Not established
Not established
Not established
Not established
10 ppm, 26 mg/m3
10 ppm, 44 mg/m3
200 ppm,
500 mg/m3
Not established
Not established
Not established
Not established
EU ILV DFG MAK
COMPOSITION/INFORMATION ON INGREDIENTSSECTION 2
EU Symbol/
R-Phrase
Ink for Ink Jet PrinterUse of the Product:
SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
April 9, 2003Revised:December 22, 2000Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 2 of 8
May cause minimal irritation. (See SECTION 11)
Eye:
May cause mild irritation and no sensitization. (See SECTION 11)
Skin:
No adverse effects are expected under intended use.
Over exposure to vapor or mist may cause respiratory tract irritation, cough, dizziness, drowsiness, headache
and nausea.
Inhalation:
May cause abdominal pain, diarrhea, dizziness, drowsiness, dullness, headache, nausea and vomiting.
Ingestion:
Not identified
Chronic Effects:
If symptoms are experienced, move victim to fresh air and obtain medical advice.
Inhalation:
Rinse mouth. Give one or two glasses of water.
If irritation or discomfort occurs, obtain medical advice immediately.
Ingestion:
Wash with water and soap or mild detergent.
If irritation persists, obtain medical advice.
Skin:
Immediately flush with lukewarm, gently flowing water for 5 minutes or until the chemical is removed.
If irritation persists, obtain medical advice immediately.
Eye:
None
Note to Physicians:
Ink tank containing magenta liquid ink with slight odor.
Emergency Overview:
Potential Health Effects and Symptoms:
First Aid Measures:
Not identified
Medical Conditions Generally known to be Aggravated by Exposure:
SECTION 3 HAZARDS IDENTIFICATION
Not classified as dangerous.
EU Classification:
SECTION 4 FIRST AID MEASURES
< Carcinogen >
No component of this ink is listed as a human carcinogen or a potential carcinogen in IARC Monographs, NTP, OSHA regulations or
Annex I to Directive 67/548/EEC.
April 9, 2003Revised:December 22, 2000Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 3 of 8
CO2 , water, foam or dry chemicals
Extinguishing Media:
None
Special Fire Fighting Procedures:
None
Unusual Fire and Explosion Hazards:
CO, CO2 and NOx
Hazardous Combustion Products:
None
Other Properties:
Avoid contact with skin, eyes and clothing.
Personal Precautions:
Do not release to sewer, surface water or ground water.
Environmental Precautions:
Wipe off with wet cloth or paper.
Method for Cleaning Up:
Use with adequate ventilation.
Avoid contact with skin, eyes and clothing.
In case of contact, wash out the contaminated area immediately.
Handling:
Keep in a cool and dry place. Protect from sunlight.
Keep away from heat and flame.
Keep out of the reach of children.
Storage:
Not established for this ink. (See also SECTION 2)
Exposure Guidelines:
Use adequate ventilation.
Engineering Controls:
Required
Not Required
Respiratory Protection:
Required
Not Required
Eye/Face Protection:
Required
Not Required
Fire Fighting Measures:
Fire and Explosive Properties (See also Section 9):
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Skin Protection:
Unsuitable Extinguishing Media:
None
Personal Protection Equipment(s):
SECTION 6 ACCIDENTAL RELEASE MEASURES
Ink for Ink Jet Printer.
For more information, please refer to the instruction of this product.
Specific Uses:
SECTION 5 FIRE FIGHTING MEASURES
SECTION 7 HANDLING AND STORAGE
April 9, 2003Revised:December 22, 2000Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 4 of 8
Slight odorOdor:
9.1 - 10.1pH:
Not availableBoiling Point/Range(°C):
Not availableMelting Point/Range(°C):
Flammability:
Not availableVapor Pressure :
Not availableVapor Density :
1.04 - 1.10Density / Specific Gravity:
MiscibleWater Solubility :
Not availableFat Solubility :
Partition Coefficient (n-Octanol/Water):
60 - 80Percent Volatile (%):
Not availableEvaporation Rate:
Stable
Unstable
Stability:
NoneConditions to Avoid:
Acids, bases, oxidizing materials and reducing agentsMaterials to Avoid:
CO, CO2 , NOx and AmmoniaHazardous Decomposition Products:
May Occur
Will Not Occur
Hazardous Polymerization:
Appearance:
Estimate : 55 - 57 (Tag Closed Cup. Combustion is not sustainable.)Flash Point(°C):
NoneExplosive Properties:
NoneOxidizing Properties:
Magenta liquid
Classified as "Combustible liquid" under OSHA-HCS.
Not classified as "flammable" or "combustible" under FHSA.
Not classified as "flammable" under 1999/45/EC.
Not availableDecomposition Temperature(°C):
NoneConditions to Avoid:
Not availableFlammable (Explosive) Limits:
Not availableAutoignition Temperature(°C):
Not available
2.0 - 2.6Viscosity (mPa s):
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
SECTION 10 STABILITY AND REACTIVITY
April 9, 2003Revised:December 22, 2000Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 5 of 8
Not available
Inhalation:
[Data of similar composition ink] Estimate LD50 > 2500 mg/kg (rat)
OECD Guidelines No.423 (1996)
96/54/EC Method B1 tris
Ingestion:
[Data of similar composition ink] Mild irritant (rabbit)
OECD Guidelines No.404 (1992)
92/69/EEC Method B4
Skin:
[Data of similar composition ink] Minimal irritant (rabbit)
OECD Guidelines No.405 (1987)
92/69/EEC Method B5
Eye:
[Data of similar composition ink] Non sensitizer (guinea pig)
OECD Guidelines No.406 (1992)
96/54/EC Method B6
Sensitization:
Ames test : Negative (test strains: S.typhimurium & E.Coli)
Mutagenicity:
Not available
Reproductive Toxicity:
Not available
Carcinogenicity:
Not available
Others:
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity:
April 9, 2003Revised:December 22, 2000Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 6 of 8
Not availableMobility:
Not available
Persistence /
Degradability:
Not availableBioaccumulation:
Not availableEcotoxicity:
Not availableOther Adverse Effects:
Disposal should be subject to federal, state and local laws.
Method of Disposal:
Not requiredSymbol & Indication:
Not required
R-Phrase:
None
Dangerous Component(s):
None
Specific Provisions in Relation to Protection of Man or the Environment:
Not regulated76/769/EEC:
Not regulated(EC)2037/2000:
Not regulated(EC)304/2003:
SECTION 13 DISPOSAL CONSIDERATION
< EU Information >
Information on the Label:
Not required
S-Phrase:
Others:
NoneUN #:
NoneUN Shipping Name:
NoneUN Classification:
NoneSpecial Precautions:
NoneUN Packing Group:
Marine Pollutant: Yes
No Chemical name (wt%):
SECTION 15 REGULATORY INFORMATION
Not required
Special Precautions under 1999/45/EC Annex V:
SECTION 12 ECOLOGICAL INFORMATION
SECTION 14 TRANSPORT INFORMATION
April 9, 2003Revised:December 22, 2000Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 7 of 8
Not required
"Ethylene glycol" (107-21-1)
SARA Title III §313:
2 - 6
None
California Proposition 65:
< USA Information >
Information on the Label
Chemical Name Weight %
Chemical Name Weight %
Signal Word:
Not required
Hazard warning:
None
Hazardous Component(s):

R11 : Highly flammable.
R22 : Harmful if swallowed.
R36 : Irritating to eyes.
R67 : Vapours may cause drowsiness or dizziness.
R52/53 : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Entirely revised.
Not required
Safety Advice:
under FHSA:
Not applicable (Manufactured article)WHMIS Controlled Product:
Not classified as hazardous according to criteria of NOHSC.Statement of Hazardous Nature:
< Canada Information >
< Australia Information >
SECTION 16 OTHER INFORMATION
April 9, 2003Revised:December 22, 2000Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 8 of 8
Literature Reference:
Abbreviations:
The information, data and recommendations set forth herein (the "Information") are presented in good faith and are believed to be correct as of the date
hereof. The company/manufacturer makes no representations as to the completeness or accuracy of the Information and disclaims responsibility for any
reliance thereon. The Information is provided upon the condition that the persons receiving same will make their own determination as to its
suitability for their purposes prior to use. Any use of the Information must be determined by the user to be in accordance with applicable Federal,
state and local laws and regulations. In no event will the company/manufacturer be responsible for damages of any nature whatsoever resulting from
the use or reliance upon the Information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION OR THE PRODUCT
TO WHICH THE INFORMATION REFERS.
- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environmental Protection Agency, 40CFR Part 372
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens
- World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of
Chemicals to Humans
- DFG, List of MAK and BAT Values
- EU Directive 76/769/EEC, 67/548/EEC, 1999/45/EC
- EU Regulation (EC)2037/2000, (EC)304/2003
- Canada Workplace Hazardous Materials Information System
- Australia National Occupational Health and Safety Commission's Approved Criteria for Classifying Hazardous Substances [NOHSC:1008]
EU: European Union.
OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA).
ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists.
EU ILV: Indicative Limit Values for Occupational Exposure under EU Directive 91/322/EEC and 2000/39/EC.
DFG MAK: MAK(Maximale Arbeitsplatzkonzentrationen) under Deutsche Forschungsgemeinschaft.
TWA: Time Weighted Average.
IARC: International Agency for Research on Cancer.
NTP: National Toxicology Program (USA).
OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA).
FHSA: Federal Hazardous Substances Act (USA).
WHMIS: Workplace Hazardous Materials Information System.
NOHSC: National Occupational Health and Safety Commission Act 1985.
April 9, 2003Revised:December 22, 2000Date of Issue:

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