Safety Data Sheet - Canon USA

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Safety Data Sheet
Issuing date : 05-Mar-2015 SDS # : TCW 0091 N - 01 US EN
Revision date : - Version : 01
SECTION 1: Product and company identification
Product Identifier
Product name GPR-54 TONER BK AMR
Product Code(s) 9436B003
Use Toner for electrophotographic machines
Details of the supplier of the safety data sheet
Supplier
Canon USA, Inc.
One Canon Park, Melville, NY 11747, USA
Phone number : 1-800-OK-CANON
Emergency phone number : 24 Hr. Emergency CHEMTREC # 1-800-424-9300
Canon Canada Inc.
6390 Dixie Road, Mississauga, Ontario L5T 1P7, Canada
Phone number : (1) 905-795-1111
Emergency phone number : 24 Hr. Emergency CHEMTREC # 1-800-424-9300
Manufacturer
Canon Inc.
30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo 146-8501, Japan
SECTION 2: Hazards identification
Emergency Overview
Black fine powder, slight plastic odor.
Classification under OSHA HCS
Not classified
US Label Elements under OSHA HCS
Symbol
Not required
Signal word
Not required
_________________________________________________________________________________________
Hazard statements
Not required
Precautionary statements
Not required
Other Information
None
US EN
Other hazards which do not result in classification
Page 1 / 7
None
_________________________________________________________________________________________
Issuing date : 05-Mar-2015 9436B003
Revision date : - GPR-54 TONER BK AMR
SECTION 3: Composition/information on ingredients
Chemical name CAS-No Weight %
Polyester resin CBI 45 - 55
Iron oxide 1317-61-9 40 - 50
Amorphous silica 7631-86-9 1 - 3
SECTION 4: First aid measures
Description of first aid measures
Inhalation Move to fresh air. Get medical attention immediately if symptoms occur.
Ingestion Rinse mouth. Drink 1 or 2 glasses of water. Get medical attention immediately if symptoms
occur.
Skin Contact Wash off immediately with soap and plenty of water. Get medical attention immediately if
symptoms occur.
Eye Contact Flush with plenty of water. Get medical attention immediately if symptoms occur.
Most important symptoms and effects, both acute and delayed
Inhalation None under normal use. Exposure to excessive amounts of dust may cause physical
irritation to respiratory tract.
Ingestion None under normal use.
Skin Contact None under normal use.
Eye Contact None under normal use. May cause slight irritation.
Chronic Effects None under normal use. Prolonged inhalation of excessive amounts of dust may cause lung
damage.
Indication of any immediate medical attention and special treatment needed
None
SECTION 5: Firefighting measures
Extinguishing media
_________________________________________________________________________________________
Suitable extinguishing media
Use CO2, dry chemical, or foam, Water.
Unsuitable extinguishing media
None
Special hazards arising from the substance or mixture
Special Hazard
May form explosive mixtures with air.
US EN Page 2 / 7
Hazardous combustion products
Carbon dioxide (CO 2), Carbon monoxide (CO)
_________________________________________________________________________________________
Issuing date : 05-Mar-2015 9436B003
Revision date : - GPR-54 TONER BK AMR
Advice for firefighters
Special protective equipment for fire-fighters
None
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid breathing dust. Avoid contact with skin, eyes and clothing.
Environmental Precautions
Keep out of waterways.
Methods and material for containment and cleaning up
Clean up promptly by scoop or vacuum. If a vacuum cleaner is used, be sure to use a model with dust explosion safety measures.
May form explosive mixtures with air.
Other Information
None
SECTION 7: Handling and storage
Precautions for safe handling
Avoid breathing dust. Avoid contact with skin, eyes and clothing. Clean contaminated surface thoroughly. Use only with adequate
ventilation.
Conditions for safe storage, including any incompatibilities
Keep in a dry, cool and well-ventilated place. Keep out of the reach of children. Incompatible with oxidizing agents.
SECTION 8: Exposure controls/personal protection
Exposure guidelines
Chemical name OSHA PEL ACGIH TLV
Amorphous silica
7631-86-9
TWA: 20 mppcf
: (80)/(% SiO2) mg/m3 TWA
None
Appropriate engineering controls None under normal use conditions.
Individual protection measures, such as personal protective equipment
Eye/face Protection Not required under normal use.
Skin Protection Not required under normal use.
Respiratory Protection Not required under normal use.
SECTION 9: Physical and chemical properties
_________________________________________________________________________________________
Information on basic physical and chemical properties
Appearance Black ; powder
Odor
US EN
Slight odor
Page 3 / 7
Odor threshold No data available
_________________________________________________________________________________________
Issuing date : 05-Mar-2015 9436B003
Revision date : - GPR-54 TONER BK AMR
pH Not Applicable
Evaporation Rate Not Applicable
Flammability (solid, gas) Not flammable; estimated
Flammability Limits in Air
Upper Flammability Limit Not Applicable
Lower Flammability Limit Not Applicable
Vapor pressure Not Applicable
Vapor Density Not Applicable
Relative density 1.4-1.8
Solubility(ies) Organic solvent; partly soluble
Partition coefficient: n-octanol/water Not Applicable
Other Information
No data available
SECTION 10: Stability and reactivity
Reactivity
None
Chemical stability
Stable
Possibility of Hazardous Reactions
None
Conditions to Avoid
None
Incompatible materials
Acids, Bases, Oxidizing agents, Reducing agents.
Hazardous Decomposition Products
Carbon dioxide (CO 2), Carbon monoxide (CO)
SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity Estimate: LD50 > 2000 mg/kg (Ingestion)
Skin corrosion/irritation Estimate: Non-irritant
Serious eye damage/eye irritation Estimate: Transient slight conjunctival irritation only.
Sensitization Estimate: Non-sensitizing
Melting/Freezing point (°C) 100-150 (Softening point)
_________________________________________________________________________________________
Boiling Point/Range (°C) Not Applicable
Flash Point (°C) Not Applicable
Autoignition Temperature (°C) No data available
Decomposition Temperature (°C)
US EN
> 200
Page 4 / 7
Viscosity (mPa s) Not Applicable
_________________________________________________________________________________________
Issuing date : 05-Mar-2015 9436B003
Revision date : - GPR-54 TONER BK AMR
Germ cell mutagenicity Estimate: Ames Test (S. typhimurium, E. coli): Negative
Carcinogenicity No data available
Reproductive Toxicity No data available
STOT - single exposure No data available
STOT - repeated exposure Muhle et al. reported pulmonary response upon chronic inhalation exposure in rats to a
toner enriched in respirable-sized particles compared to commercial toner. No pulmonary
change was found at 1 mg/m3 which is most relevant to potential human exposure. A
minimal to mild degree of fibrosis was noted in 22% of the animals at 4 mg/m3, and a mild
to moderate degree of fibrosis was observed in 92% of the animals at 16 mg/m3.
These findings are attributed to "lung overloading", a generic response to excessive
amounts of any dust retained in the lung for a prolonged interval.
Aspiration hazard No data available
Other Information No data available
SECTION 12: Ecological information
Toxicity
Ecotoxicity effects
Fish, 96h LL50 > 1000 mg/l (WAF)
Crustaceans, 48h EL50 > 1000 mg/l (WAF)
Algae, ErL50(0-72h) > 1000 mg/l (WAF)
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13: Disposal considerations
Waste treatment methods
DO NOT put toner or a toner container into fire. Heated toner may cause severe burns. DO NOT dispose of a toner container in a
plastic crusher. Use a facility with dust explosion prevention measures. Finely dispersed particles form explosive mixtures with air.
Dispose of in accordance with local regulations.
SECTION 14: Transport information
_________________________________________________________________________________________
UN number None
US EN Page 5 / 7
_________________________________________________________________________________________
Issuing date : 05-Mar-2015 9436B003
Revision date : - GPR-54 TONER BK AMR
SECTION 15: Regulatory information
Safety, health and environmental regulations specific for the product in question
TSCA Sec. 4,5,6,7,8,12b None
SARA Title III Sec. 313 None
California Proposition 65 None
CEPA Sec. 81 None
HPA (WHMIS) None (Manufactured Article)
Other Information None
SECTION 16: Other information
Key literature references and sources for data
- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environmental Protection Agency, 40CFR Part 372
- U.S. Environmental Protection Agency, 40CFR Part 700-799
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens
- World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the
Carcinogenic Risk of Chemicals to Humans
- California EPA, Code of Regulations Title 27. Division 4. Chapter 1. Safe Drinking Water and Toxic Enforcement Act of 1986
- Environment Canada, Canadian Environmental Protection Act, 1999
- Health Canada, Hazardous Products Act, and Controlled Products Regulations
- Canada Workplace Hazardous Materials Information System
Key or legend to abbreviations and acronyms used in the safety data sheet
- OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA)
- FHSA: Federal Hazardous Substances Act
- IARC: International Agency for Research on Cancer
- OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA)
- ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists
- TWA: Time Weighted Average
- STEL: Short Term Exposure Limit
- TSCA: Toxic Substances Control Act
- SARA Title III: SARA Title III of the Superfund Amendments and Reauthorization Act of 1986
- Proposition 65: Safe Drinking Water and Toxic Enforcement Act of 1986
- CEPA: Canadian Environmental Protection Act, 1999
- HPA: Hazardous Products Act
- WHMIS: Workplace Hazardous Materials Information System
- CBI: Confidential Business Information
Issuing date : 05-Mar-2015
Revision date : UN Proper Shipping Name None
Transport Hazard Class None
Packing Group None
Environmental Hazards No special environmental precautions required.
_________________________________________________________________________________________
Special Precautions for users None
US EN Page 6 / 7
Transport in bulk according to Annex II of
MARPOL 73/78 and the IBC Code
Not Applicable
_________________________________________________________________________________________
Issuing date : 05-Mar-2015 9436B003
Revision date : - GPR-54 TONER BK AMR
Revision Note None
Disclaimer
The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered as a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
material or in any process, unless specified in the text.
_________________________________________________________________________________________
US EN Page 7 / 7

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