SAFETY DATA SHEET - Soudal

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Page 1/8
SAFETY DATA SHEET
According to Safe Work Australia
Printing date 28.01.2015 Revision: 28.01.2015
38.0.35
1 . IDENTIFICATION: PRODUCT IDENTIFIER AND CHEMICAL IDENTITY
Product Name: SOUDAL PRIMER 100
Other Means of Identification: Mixture
Product Code: 44711
Recommended Use of the Chemical and Restriction on Use: Primer
Details of Manufacturer or Importer:
Soudal Australia Pty Ltd
Unit 1, 29 Prince William Drive
Seven Hills NSW 2147
Phone Number: 02 8678 7449
Emergency telephone number: 1300 507 011
2 . HAZARDS IDENTIFICATION
Hazardous Nature:
Classified as Hazardous according to criteria of National Occupational Health & Safety Commission
(NOHSC), Australia.
Classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by
Road and Rail (7th edition).
flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
health hazard
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335-H336 May cause respiratory irritation. May cause drowsiness or dizziness.
Signal Word Danger
Hazard Statements
H226 Flammable liquid and vapour.
H317 May cause an allergic skin reaction.
H335-H336 May cause respiratory irritation. May cause drowsiness or dizziness.
H304 May be fatal if swallowed and enters airways.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
(Contd. on page 2)
Page 2/8
SAFETY DATA SHEET
According to Safe Work Australia
Printing date 28.01.2015 Revision: 28.01.2015
Product Name: SOUDAL PRIMER 100
(Contd. of page 1)
38.0.35
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P240 Ground/bond container and receiving equipment.
P233 Keep container tightly closed.
P242 Use only non-sparking tools.
P273 Avoid release to the environment.
P243 Take precautionary measures against static discharge.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P321 Specific treatment (see on this label).
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P331 Do NOT induce vomiting.
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
P391 Collect spillage.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P302+P352 IF ON SKIN: Wash with plenty of water.
P312 Call a POISON CENTER/doctor if you feel unwell.
P362+P364 Take off contaminated clothing and wash it before reuse.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national regulations.
3 . COMPOSITION AND INFORMATION ON INGREDIENTS
Chemical Characterization: Mixtures
Description: Mixture of substances listed below with nonhazardous additions.
Hazardous Components:
108-67-8 mesitylene
Flam. Liq. 3, H226; Aquatic Chronic 2, H411; STOT SE 3, H335
2.5-<25%
100-41-4 Benzene, ethylFlam. Liq. 2, H225; Acute Tox. 4, H332
10-<25%
140921-24-0 1,6-hexanediyl-bis(2-(2-(1-ethylpentyl)-3-oxazolidinyl)ethyl)carbamate
Skin Sens. 1, H317
10-<25%
95-63-6 Benzene, 1,2,4-trimethylFlam. Liq. 3, H226; Aquatic Chronic 2, H411; Acute Tox. 4, H332; Skin
Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335
10-<25%
64742-95-6 Solvent naphtha (petroleum), light arom.
Asp. Tox. 1, H304; Aquatic Chronic 2, H411; Acute Tox. 4, H332; STOT
SE 3, H335; H227; Acute Tox. 5, H313; H401
10-<25%
1330-20-7 Benzene, dimethylFlam. Liq. 2, H225; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2,
H315
10-<25%
540-84-1 2,2,4-trimethylpentane
Flam. Liq. 2, H225; Asp. Tox. 1, H304; Aquatic Acute 1, H400; Aquatic
Chronic 1, H410; Skin Irrit. 2, H315; STOT SE 3, H336
1-2.5%
(Contd. on page 3)
Page 3/8
SAFETY DATA SHEET
According to Safe Work Australia
Printing date 28.01.2015 Revision: 28.01.2015
Product Name: SOUDAL PRIMER 100
(Contd. of page 2)
38.0.35
4098-71-9 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate
Acute Tox. 3, H331; Resp. Sens. 1, H334; Aquatic Chronic 2, H411;
Skin Irrit. 2, H315; Eye Irrit. 2A, H319; Skin Sens. 1, H317; STOT SE 3, H335
0.3-<0.5%
53880-05-0 Cyclohexane, 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl-, homopolymer
Skin Sens. 1, H317; STOT SE 3, H335
>20%
98-82-8 cumene
Flam. Liq. 3, H226; Asp. Tox. 1, H304; Aquatic Chronic 2, H411;
STOT SE 3, H335
1-<10%
4 . FIRST AID MEASURES
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Seek medical attention if breathing problems develop.
Skin Contact:
In case of skin contact, immediately remove contaminated clothing and wash affected areas with water and
soap. Seek medical attention if symptoms occur.
Eye Contact:
In case of eye contact, rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Seek medical attention.
Ingestion:
If swallowed, do not induce vomiting. If vomiting occurs spontaneously, keep head below hips to prevent
aspiration. Do not give anything by mouth to an unconscious person. Seek immediate medical attention.
5 . FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Polyvalent foam, BC powder and carbon dioxide.
Specific Hazards Arising from the Chemical:
Containers close to fire should be removed if safe to do so. Use water to keep fire exposed containers cool.
Vapors are heavier than air and may travel long distance to a source of ignition and flash back.
Hazardous combustion products include oxides of carbon and nitrous vapours.
Special Protective Equipment and Precautions for Fire Fighters:
Wear Safe Work Australia approved self-contained breathing apparatus and full protective clothing.
6 . ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures:
Wear Safe Work Australia approved self-contained breathing apparatus and full protective clothing. Evacuate
all non-essential personnel from affected area. Do not breathe vapours. Ensure adequate ventilation.
Extinguish all sources of ignition. Avoid sparks and open flames. No smoking.
Environmental Precautions:
In the event of a major spill, prevent spillage from entering drains or water courses.
Methods and Materials for Containment and Cleaning Up:
Stop leak if safe to do so and absorb spill with s and, earth, vermiculite or some other absorbent material.
Collect the spilled material and place into a suitable container for disposal. Use only non-sparking tools. Clean
contaminated surfaces with an excess of water.
7 . HANDLING AND STORAGE
Precautions for Safe Handling:
Use of safe work practices are recommended to avoid eye or skin contact and inhalation of vapours.
Food, beverages and tobacco products should not be stored or consumed where this material is in use.
(Contd. on page 4)
Page 4/8
SAFETY DATA SHEET
According to Safe Work Australia
Printing date 28.01.2015 Revision: 28.01.2015
Product Name: SOUDAL PRIMER 100
(Contd. of page 3)
38.0.35
Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and
other protective equipment before storage or re-use. Provide eyewash fountains and safety showers in close
proximity to points of potential exposure.
Conditions for Safe Storage:
Store in a cool, dry and well ventilated area. Keep container tightly closed when not in use. Protect from direct
sunlight, heat, sparks, open flames and other sources of ignition. Keep away from strong oxidising agents and
acids. Maximum storage time is one year.
8 . EXPOSURE CONTROLS AND PERSONAL PROTECTION
Exposure Standards:
100-41-4 Benzene, ethylNES STEL: 543 mg/m³, 125 ppm
TWA: 434 mg/m³, 100 ppm
1330-20-7 Benzene, dimethylNES STEL: 655 mg/m³, 150 ppm
TWA: 350 mg/m³, 80 ppm
4098-71-9 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate
NES STEL: 0.07 mg/m³
TWA: 0.02 mg/m³
Sen, as -NCO
98-82-8 cumene
NES STEL: 375 mg/m³, 75 ppm
TWA: 125 mg/m³, 25 ppm
Sk 108-67-8 mesitylene
TWA 100 mg/m³, 20 ppm (EU)
95-63-6 Benzene, 1,2,4-trimethylTWA 100 mg/m³, 20 ppm (EU)
Engineering Controls:
Maintain air concentration below occupational exposure standards, providing adequate ventilation. Use
explosion-proof ventilating equipment.
Respiratory Protection:
Use a Safe Work Australia approved full face supplied ai r respirator if high airborne concentrations of the
material are present. See Australian Standards AS/NZS 1715 and 1716 for more information.
Skin Protection:
Protective gloves (teflon, viton, nitrile rubber) and protective clothing. See Australian Standards AS/NZS 2161,
2210.1 and 2210.2 for more information.
Eye and Face Protection:
Safety glasses with top and side shields or goggles. See Australian/New Zealand Standards AS/NZS 1336
and 1337 for more information.
9 . PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Form: Liquid
Colour: Variable in colour, depending on the composition.
Odour: Solvent like odour
Odour Threshold: Not determined.
(Contd. on page 5)
Page 5/8
SAFETY DATA SHEET
According to Safe Work Australia
Printing date 28.01.2015 Revision: 28.01.2015
Product Name: SOUDAL PRIMER 100
(Contd. of page 4)
38.0.35
pH-Value: Not determined.
Melting point/Melting range: Not determined.
Initial Boiling Point/Boiling Range: Not determined.
Flash Point: 47 °C
Flammability: Flammable
Auto-ignition Temperature: Not determined.
Decomposition Temperature: Not determined.
Explosion Limits:
Lower: Not determined.
Upper: Not determined.
Vapour Pressure: Not determined.
Density: Not determined.
Relative Density at 20 °C: 1 g/cm³
Vapour Density at 20 °C: >1 g/cm³
Evaporation Rate: Not determined.
VOC: 78 %
10 . STABILITY AND REACTIVITY
Possibility of Hazardous Reactions: Hazardous polymerisation will not occur.
Chemical Stability: Stable at ambient temperature and under normal conditions of use.
Conditions to Avoid: Heat, sparks, open flames and other sources of ignition.
Incompatible Materials: No further relevant information available.
Hazardous Decomposition Products: Oxides of carbon and nitrous vapours.
11 . TOXICOLOGICAL INFORMATION
Toxicity:
LD₅₀/LC₅₀ Values Relevant for Classification:
100-41-4 Benzene, ethylOral LD₅₀ 3500 mg/kg (rat)
Dermal LD₅₀ 17800 mg/kg (rabbit)
95-63-6 Benzene, 1,2,4-trimethylOral LD₅₀ 5000 mg/kg (rat)
64742-95-6 Solvent naphtha (petroleum), light arom.
Oral LD₅₀ >6800 mg/kg (rat)
Dermal LD₅₀ >3400 mg/kg (rab)
Inhalation LC₅₀/4 h >10.2 mg/l (rat)
1330-20-7 Benzene, dimethylOral LD₅₀ 4300 mg/kg (rat)
Dermal LD₅₀ 2000 mg/kg (rabbit)
53880-05-0 Cyclohexane, 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl-, homopolymer
Oral LD50 > 5000 mg/kg (rat)
Inhalation LC50 > 5.01 mg/L (rat)
4098-71-9 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate
Oral LD50 > 2500 mg/kg (rat)
(Contd. on page 6)
Page 6/8
SAFETY DATA SHEET
According to Safe Work Australia
Printing date 28.01.2015 Revision: 28.01.2015
Product Name: SOUDAL PRIMER 100
(Contd. of page 5)
38.0.35
108-67-8 mesitylene
Inhalation LC50 24 mg/L / 4 hour (rat)
98-82-8 cumene
Oral LD₅₀ 1400 mg/kg (rat)
Dermal LD₅₀ 12300 mg/kg (rabbit)
Inhalation LC₅₀/4 h 24.7 mg/l (mouse)
540-84-1 2,2,4-trimethylpentane
Oral LD50 3310 mg/kg (rat)
Dermal LD50 >2000 mg/kg (rabbit)
Inhalation LC50 > 14.5 mg/L / 4 hour (rat)
Acute Health Effects
Inhalation:
May cause irritation of the nasal mucous membranes and the respiratory tract. Expo sure to high
concentrations may cause narcosis.
Skin: May cause slight skin irritation.
Eye: May cause slight eye irritation.
Ingestion: Ingestion is not considered a potential route of exposure.
Skin Corrosion / Irritation: Based on classification principles, the classification criteria are not met.
Serious Eye Damage / Irritation: Based on classification principles, the classification criteria are not met.
Respiratory or Skin Sensitisation: Sensitization possible through skin contact.
Germ Cell Mutagenicity: Based on classification principles, the classification criteria are not met.
Carcinogenicity:
Xylenes is classified by IARC as Group 3 - Not classifiable as to its carcinogenicity to humans.
Ethylbenzene and cumene are classified by IARC as Group 2B - Possibly carcinogenic to humans.
Reproductive Toxicity: Based on classification principles, the classification criteria are not met.
Specific Target Organ Toxicity (STOT) - Single Exposure:
May cause respiratory irritation.
May cause drowsiness and dizziness.
Specific Target Organ Toxicity (STOT) - Repeated Exposure:
Based on classification principles, the classification criteria are not met.
Aspiration Hazard: May be fatal if swallowed and enters airways.
Chronic Health Effects: Repeated or prolonged contact may cause skin rash and inflammation.
Existing Conditions Aggravated by Exposure: No information available
12 . ECOLOGICAL INFORMATION
Ecotoxicity:
Aquatic toxicity:
Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
53880-05-0 Cyclohexane, 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl-, homopolymer
EC50 / 48 h 83.7 mg/L (daphnia)
108-67-8 mesitylene
LC50 / 96 h 13 mg/L (fish)
(Contd. on page 7)
Page 7/8
SAFETY DATA SHEET
According to Safe Work Australia
Printing date 28.01.2015 Revision: 28.01.2015
Product Name: SOUDAL PRIMER 100
(Contd. of page 6)
38.0.35
95-63-6 Benzene, 1,2,4-trimethylEC50 / 48 h 3.6 mg/L (daphnia)
LC50 / 96 h 7.72 mg/L (flathead minnows)
98-82-8 cumene
LC50 / 96 h 2.7 mg/L (fish)
1330-20-7 Benzene, dimethylEC50 / 48 h 7.4 mg/L (daphnia)
LC50 / 96 h 3.77 mg/L (fish)
100-41-4 Benzene, ethylEC50 / 48 h 75 mg/L (daphnia)
LC50 / 96 h 4.2 mg/L (fish)
Persistence and Degradability: No information available
Bioaccumulative Potential: No information available
Mobility in Soil: No information available
13 . DISPOSAL CONSIDERATIONS
Disposal Methods and Containers: Dispose according to applicable local and state government regulations.
Special Precautions for Landfill or Incineration:
Please consult your state Land Waste Management Authority for more information.
14 . TRANSPORT INFORMATION
UN Number 1263
Proper Shipping Name PAINT (including paint, lacquer, enamel, stain, shellac,
varnish, polish, liquid filler and liquid lacquer base) or
PAINT RELATED MATERIAL (including paint thinning or
reducing compound)
Dangerous Goods Class 3
Packing Group:
ADG, IMDG, IATA III
Marine pollutant: Yes
Symbol (fish and tree)
Hazchem Code: .3Y
Special Provisions: 163, 223
Limited Quantities: 5L
Packagings & IBCs - Packing Instruction: P001, IBC03, LP01
Packagings & IBCs - Special Packing Provisions: PP1
Portable Tanks & Bulk Containers - Instructions: T2
Portable Tanks & Bulk Containers - Special
Provisions: TP1, TP29
(Contd. on page 8)
Page 8/8
SAFETY DATA SHEET
According to Safe Work Australia
Printing date 28.01.2015 Revision: 28.01.2015
Product Name: SOUDAL PRIMER 100
(Contd. of page 7)
38.0.35
15 . REGULATORY INFORMATION
Australian Inventory of Chemical Substances:
53880-05-0 Cyclohexane, 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl-, homopolymer
108-67-8 mesitylene
100-41-4 Benzene, ethyl95-63-6 Benzene, 1,2,4-trimethyl64742-95-6 Solvent naphtha (petroleum), light arom.
540-84-1 2,2,4-trimethylpentane
4098-71-9 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate
Standard for the Uniform Scheduling of Drugs and Poisons (SUSMP) - Poison Schedule:
Poisons Schedule: 5
16 . OTHER INFORMATION
Creation Date: 10.02.2014
Prepared by: MSDS.COM.AU Pty Ltd www.msds.com.au
Abbreviations and acronyms:
ADG: Australian Dangerous Goods
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC₅₀: Lethal concentration, 50 percent
LD₅₀: Lethal dose, 50 percent
IARC: International Agency for Research on Cancer
STEL: Short Term Exposure Limit
TWA: Time Weighted Average
NES: National Exposure Standard (Safe Work Australia - Workplace Exposure Standards For Airborne Contaminants)
Data compared to the previous version altered. Section 1.
Disclaimer
This MSDS is prepared in accord with the Safe Work Australia document “Code of Practice for the
Preparation of Safety Data Sheets for Hazardous Chemicals - December 2011”
The information contained in this material safety data sheet is provided in good faith and is believed to be
accurate at the date of issuance. Soudal Australia Pty Ltd makes no representati on of the accuracy or
comprehensiveness of the information and to the full extent allowed by law excludes all liability for any loss or
damage related to the supply or use of the information in this material safety data sheet. MSDS.COM.AU Pty
Ltd is not in a position to warrant the accuracy of the data herein. The user is cautioned to make their own
determinations as to the suitability of the information provided to the particular circumstances in which the
product is used.

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