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HOLD
TM
SPRAY-ON TRAY ADHESIVE
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
Revision Date: 11/11/2014 Date of issue: 11/11/2014 Supersedes Date: 02/12/2013 Version: 1.0
11/11/2014 EN (English US) 1/12
SECTION 1: IDENTIFICATION
Product Identifier
Product Name: HOLD
TM
SPRAY-ON TRAY ADHESIVE
Product Code: 011461-000
Intended Use of the Product
Designed to provide an improved retaining grip between the impression tray and any alginate and hydrocolloid impression material.
Name, Address, and Telephone of the Responsible Party
Company
Water Pik, Inc.
1730 East Prospect Road
Fort Collins, CO 80553-0001
800/525-2020 (8 am- 4pm MST)
Emergency Telephone Number
Emergency Number : 800/424-9300 (24 Hr: CHEMTREC)
SECTION 2: HAZARDS IDENTIFICATION
Classification of the Substance or Mixture
Classification (GHS-US)
Simple Asphy
Flam. Aerosol 1 H222
Skin Irrit. 2 H315
Eye Irrit. 2A H319
Repr. 2 H361
STOT SE 3 H336
STOT RE 2 H373
Asp. Tox. 1 H304
Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) :
GHS02
GHS07
GHS08
Signal Word (GHS-US) : Danger
Hazard Statements (GHS-US) : H222 - Extremely flammable aerosol.
H304 - May be fatal if swallowed and enters airways.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H336 - May cause drowsiness or dizziness.
H361 - Suspected of damaging fertility or the unborn child.
H373 - May cause damage to organs through prolonged or repeated exposure.
May displace oxygen and cause rapid suffocation.
Precautionary Statements (GHS-US) : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from sparks, open flames, heat, hot surfaces. - No smoking.
P211 - Do not spray on an open flame or other ignition source.
P251 - Pressurized container: Do not pierce or burn, even after use.
P260 - Do not breathe gas, mist, spray.
P264 - Wash hands, forearms, and exposed areas thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear protective clothing, protective gloves, eye protection.
P301+P310 - IF SWALLOWED: Immediately call POISON CENTER/doctor.
HOLD
TM
SPRAY-ON TRAY ADHESIVE
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
11/11/2014 EN (English US) 2/12
P302+P352 - IF ON SKIN: Wash with plenty of water.
P304+P340 - IF INHALED: Remove person to fresh air and keep at rest in a position
comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - If exposed or concerned: Get medical advice/attention.
P312 - Call POISON CENTER/doctor if you feel unwell.
P321 - Specific treatment (see Section 4).
P331 - Do NOT induce vomiting.
P332+P337+P313 - If skin or eye irritation occurs: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
P405 - Store locked up.
P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P501 - Dispose of contents/container in accordance with local, regional, national, territorial,
provincial, and international regulations.
Other Hazards Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or
burn, even after use. Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions.
Unknown Acute Toxicity (GHS-US) Not available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Mixture
Name Product Identifier % (w/w) Classification (GHS-US)
Isopropyl alcohol (CAS No) 67-63-0 40 - 50 Flam. Liq. 2, H225
Eye Irrit. 2A, H319
STOT SE 3, H336
Propane (CAS No) 74-98-6 10 - 15 Simple Asphy
Flam. Gas 1, H220
Liquefied gas, H280
Butane (CAS No) 106-97-8 10 - 15 Simple Asphy
Flam. Gas 1, H220
Liquefied gas, H280
Toluene (CAS No) 108-88-3 10 - 15 Flam. Liq. 2, H225
Skin Irrit. 2, H315
Repr. 2, H361
STOT SE 3, H336
STOT RE 2, H373
Asp. Tox. 1, H304
Aquatic Acute 2, H401
Aquatic Chronic 3, H412
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
Description of First Aid Measures
General: Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention.
Inhalation: When symptoms occur: go into open air and ventilate suspected area. Remove to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell.
Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. If skin irritation occurs: Get
medical advice/attention. Wash contaminated clothing before reuse.
Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do so. Continue
rinsing. Obtain medical attention if irritation persists.
Ingestion: Rinse mouth. Do NOT induce vomiting. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
Most Important Symptoms and Effects Both Acute and Delayed
General: Causes irritation. Asphyxiant gas. May cause drowsiness and dizziness. Aspiration hazard. There are potential chronic
health effects to consider.
HOLD
TM
SPRAY-ON TRAY ADHESIVE
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
11/11/2014 EN (English US) 3/12
Inhalation: Excessive exposure may cause central nervous system effects may include headache, dizziness, loss of balance and
coordination, unconsciousness, coma, respiratory failure, and death. Asphyxiant gas, can be fatal. May cause damage to the blood,
central nervous system, and cardiovascular system. High concentrations of gas can cause unconciousness and death. Has rotten egg
smell but is not a good indicator of the presence of gas as olifactory fatigue (loss of smell) occurs rapidly. Being under the influence
of alcohol may enhance the effects of this product.
Skin Contact: Causes skin irritation.
Eye Contact: Causes serious eye irritation.
Ingestion: The major health threat of ingestion occurs from the danger of aspiration(breathing) of liquid drops into the lungs,
particularly from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage, respiratory failure
and even death.
Chronic Symptoms: Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or
repeated exposure.
Indication of Any Immediate Medical Attention and Special Treatment Needed
If exposed or concerned, get medical advice and attention.
SECTION 5: FIRE-FIGHTING MEASURES
Extinguishing Media
Special Hazards Arising From the Substance or Mixture
Advice for Firefighters
Firefighting Instructions: Exercise caution when fighting any chemical fire. Use water spray or fog for cooling exposed containers. In
case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Use
self-contained breathing apparatus when fighting fire in an enclosed area.
Hazardous Combustion Products: Carbon oxides (CO, CO2). Hydrocarbons.
Reference to Other Sections
Refer to section 9 for flammability properties.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Isolate from fire, if possible, without unnecessary risk. Remove ignition sources. Use special care to avoid static
electric charges. Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Do not breathe gas/vapor/aerosol. Use only
outdoors or in a well-ventilated area. Handle in accordance with good industrial hygiene and safety practice.
For Non-Emergency Personnel
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
For Emergency Personnel
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Ventilate area.
Environmental Precautions Prevent entry to sewers and public waters. Contact competent authorities after a spill.
Methods and Material for Containment and Cleaning Up
For Containment: Stop leak if safe to do so.
Methods for Cleaning Up: Stop the source of the release, if safe to do so. Consider the use of water spray to disperse vapors. Isolate
the area until gas has dispersed. Ventilate and gas test area before entering. Collect the residue by means of a non-combustible
absorbent material.
Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection.
SECTION 7: HANDLING AND STORAGE
Precautions for Safe Handling
Additional Hazards When Processed: Pressurized container: Do not pierce or burn, even after use.
Suitable Extinguishing Media: Water spray, fog, carbon dioxide (CO2), alcohol-resistant foam, or dry chemical.
Unsuitable Extinguishing Media: Use of heavy stream of water may spread fire.
Fire Hazard: Extremely flammable aerosol. The gas is heavier than air and may travel along the ground; distant ignition possible.
Explosion Hazard: Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries.
Reactivity: Hazardous reactions will not occur under normal conditions.
HOLD
TM
SPRAY-ON TRAY ADHESIVE
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
11/11/2014 EN (English US) 4/12
Handling Temperature: ≤ 50 °C (122 °F)
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas
with mild soap and water before eating, drinking, or smoking and again when leaving work. Wash hands and forearms thoroughly
after handling.
Conditions for Safe Storage, Including Any Incompatibilities
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep in fireproof place.
Store locked up. Keep away from heat and direct sunlight.
Incompatible Materials: Strong acids. Strong bases. Strong oxidizers.
Storage Temperature: ≤ 50 °C (122 °F)
Special Rules on Packaging: Keep only in the original container.
Specific End Use(s) Designed to provide an improved retaining grip between the impression tray and any alginate and hydrocolloid
impression material.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters
Propane (74-98-6)
USA ACGIH ACGIH TWA (ppm) 1000 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 1800 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm
USA NIOSH NIOSH REL (TWA) (mg/m³) 1800 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 1000 ppm
USA IDLH US IDLH (ppm) 2100 ppm (10% LEL)
Alberta OEL TWA (ppm) 1000 ppm
British Columbia OEL TWA (ppm) 1000 ppm
Manitoba OEL TWA (ppm) 1000 ppm
Newfoundland & Labrador OEL TWA (ppm) 1000 ppm
Nova Scotia OEL TWA (ppm) 1000 ppm
Ontario OEL TWA (ppm) 1000 ppm
Prince Edward Island OEL TWA (ppm) 1000 ppm
Québec VEMP (mg/m³) 1800 mg/m³
Québec VEMP (ppm) 1000 ppm
Saskatchewan OEL STEL (ppm) 1250 ppm
Saskatchewan OEL TWA (ppm) 1000 ppm
Butane (106-97-8)
USA ACGIH ACGIH STEL (ppm) 1000 ppm
USA NIOSH NIOSH REL (TWA) (mg/m³) 1900 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 800 ppm
Alberta OEL TWA (ppm) 1000 ppm
British Columbia OEL STEL (ppm) 750 ppm
British Columbia OEL TWA (ppm) 600 ppm
Manitoba OEL STEL (ppm) 1000 ppm
New Brunswick OEL TWA (mg/m³) 1900 mg/m³
New Brunswick OEL TWA (ppm) 800 ppm
Newfoundland & Labrador OEL STEL (ppm) 1000 ppm
Nova Scotia OEL STEL (ppm) 1000 ppm
Nunavut OEL STEL (mg/m³) 2576 mg/m³
Nunavut OEL STEL (ppm) 1000 ppm
Nunavut OEL TWA (mg/m³) 1901 mg/m³
Nunavut OEL TWA (ppm) 800 ppm
Northwest Territories OEL STEL (mg/m³) 2576 mg/m³
Northwest Territories OEL STEL (ppm) 1000 ppm
Northwest Territories OEL TWA (mg/m³) 1901 mg/m³
HOLD
TM
SPRAY-ON TRAY ADHESIVE
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
11/11/2014 EN (English US) 5/12
Northwest Territories OEL TWA (ppm) 800 ppm
Ontario OEL TWA (ppm) 800 ppm
Prince Edward Island OEL STEL (ppm) 1000 ppm
Québec VEMP (mg/m³) 1900 mg/m³
Québec VEMP (ppm) 800 ppm
Saskatchewan OEL STEL (ppm) 1250 ppm
Saskatchewan OEL TWA (ppm) 1000 ppm
Yukon OEL STEL (mg/m³) 1600 mg/m³
Yukon OEL STEL (ppm) 750 ppm
Yukon OEL TWA (mg/m³) 1400 mg/m³
Yukon OEL TWA (ppm) 600 ppm
Toluene (108-88-3)
USA ACGIH ACGIH TWA (ppm) 20 ppm
USA OSHA OSHA PEL (TWA) (ppm) 200 ppm
USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm
USA NIOSH NIOSH REL (TWA) (mg/m³) 375 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 100 ppm
USA NIOSH NIOSH REL (STEL) (mg/m³) 560 mg/m³
USA NIOSH NIOSH REL (STEL) (ppm) 150 ppm
USA IDLH US IDLH (ppm) 500 ppm
Alberta OEL TWA (mg/m³) 188 mg/m³
Alberta OEL TWA (ppm) 50 ppm
British Columbia OEL TWA (ppm) 20 ppm
Manitoba OEL TWA (ppm) 20 ppm
New Brunswick OEL TWA (mg/m³) 188 mg/m³
New Brunswick OEL TWA (ppm) 50 ppm
Newfoundland & Labrador OEL TWA (ppm) 20 ppm
Nova Scotia OEL TWA (ppm) 20 ppm
Nunavut OEL STEL (mg/m³) 560 mg/m³
Nunavut OEL STEL (ppm) 150 ppm
Nunavut OEL TWA (mg/m³) 375 mg/m³
Nunavut OEL TWA (ppm) 100 ppm
Northwest Territories OEL STEL (mg/m³) 560 mg/m³
Northwest Territories OEL STEL (ppm) 150 ppm
Northwest Territories OEL TWA (mg/m³) 375 mg/m³
Northwest Territories OEL TWA (ppm) 100 ppm
Ontario OEL TWA (ppm) 20 ppm
Prince Edward Island OEL TWA (ppm) 20 ppm
Québec VEMP (mg/m³) 188 mg/m³
Québec VEMP (ppm) 50 ppm
Saskatchewan OEL STEL (ppm) 60 ppm
Saskatchewan OEL TWA (ppm) 50 ppm
Yukon OEL STEL (mg/m³) 560 mg/m³
Yukon OEL STEL (ppm) 150 ppm
Yukon OEL TWA (mg/m³) 375 mg/m³
Yukon OEL TWA (ppm) 100 ppm
Isopropyl alcohol (67-63-0)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 400 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 980 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 400 ppm
HOLD
TM
SPRAY-ON TRAY ADHESIVE
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
11/11/2014 EN (English US) 6/12
USA NIOSH NIOSH REL (TWA) (mg/m³) 980 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 400 ppm
USA NIOSH NIOSH REL (STEL) (mg/m³) 1225 mg/m³
USA NIOSH NIOSH REL (STEL) (ppm) 500 ppm
USA IDLH US IDLH (ppm) 2000 ppm (10% LEL)
Alberta OEL STEL (mg/m³) 984 mg/m³
Alberta OEL STEL (ppm) 400 ppm
Alberta OEL TWA (mg/m³) 492 mg/m³
Alberta OEL TWA (ppm) 200 ppm
British Columbia OEL STEL (ppm) 400 ppm
British Columbia OEL TWA (ppm) 200 ppm
Manitoba OEL STEL (ppm) 400 ppm
Manitoba OEL TWA (ppm) 200 ppm
New Brunswick OEL STEL (mg/m³) 1230 mg/m³
New Brunswick OEL STEL (ppm) 500 ppm
New Brunswick OEL TWA (mg/m³) 983 mg/m³
New Brunswick OEL TWA (ppm) 400 ppm
Newfoundland & Labrador OEL STEL (ppm) 400 ppm
Newfoundland & Labrador OEL TWA (ppm) 200 ppm
Nova Scotia OEL STEL (ppm) 400 ppm
Nova Scotia OEL TWA (ppm) 200 ppm
Nunavut OEL STEL (mg/m³) 1228 mg/m³
Nunavut OEL STEL (ppm) 500 ppm
Nunavut OEL TWA (mg/m³) 983 mg/m³
Nunavut OEL TWA (ppm) 400 ppm
Northwest Territories OEL STEL (mg/m³) 1228 mg/m³
Northwest Territories OEL STEL (ppm) 500 ppm
Northwest Territories OEL TWA (mg/m³) 983 mg/m³
Northwest Territories OEL TWA (ppm) 400 ppm
Ontario OEL STEL (ppm) 400 ppm
Ontario OEL TWA (ppm) 200 ppm
Prince Edward Island OEL STEL (ppm) 400 ppm
Prince Edward Island OEL TWA (ppm) 200 ppm
Québec VECD (mg/m³) 1230 mg/m³
Québec VECD (ppm) 500 ppm
Québec VEMP (mg/m³) 985 mg/m³
Québec VEMP (ppm) 400 ppm
Saskatchewan OEL STEL (ppm) 400 ppm
Saskatchewan OEL TWA (ppm) 200 ppm
Yukon OEL STEL (mg/m³) 1225 mg/m³
Yukon OEL STEL (ppm) 500 ppm
Yukon OEL TWA (mg/m³) 980 mg/m³
Yukon OEL TWA (ppm) 400 ppm
Exposure Controls
Appropriate Engineering Controls: Ensure all national/local regulations are observed. Gas detectors should be used when
flammable gases/vapors may be released. Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment: Gloves. Protective goggles. Protective clothing. Insufficient ventilation: wear respiratory protection.
Materials for Protective Clothing: Chemically resistant materials and fabrics.
HOLD
TM
SPRAY-ON TRAY ADHESIVE
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
11/11/2014 EN (English US) 7/12
Hand Protection: Wear chemically resistant protective gloves.
Eye Protection: Chemical goggles or safety glasses.
Skin and Body Protection: Wash contaminated clothing before reuse.
Respiratory Protection: Use a NIOSH-approved respirator or self-contained breathing apparatus whenever exposure may exceed
established Occupational Exposure Limits.
Other Information: When using, do not eat, drink or smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on Basic Physical and Chemical Properties
Physical State : Liquid Aerosol
Appearance : Pressurized gas containing a clear-amber colored liquid
Odor : Alcohol-solvent
Odor Threshold : Not available
pH : Not available
Evaporation Rate : Not available
Melting Point : Not available
Freezing Point : Not available
Boiling Point : Not available
Flash Point : Not available
Auto-ignition Temperature : Not available
Decomposition Temperature : Not available
Flammability (solid, gas) : Not available
Lower Flammable Limit : 1 %
Upper Flammable Limit : 12 %
Vapor Pressure : 50 psig
Relative Vapor Density at 20 °C : Heavier than air
Relative Density : 0.8 - 0.9
Specific Gravity : Not available
Solubility : Not available
Partition Coefficient: N-octanol/water : Not available
Viscosity : Not available
Explosion Data – Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact.
Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge.
SECTION 10: STABILITY AND REACTIVITY
Reactivity: Hazardous reactions will not occur under normal conditions.
Chemical Stability: Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Extreme risk of explosion by
shock, friction, fire or other sources of ignition.
Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Open flame. Overheating.
Incompatible Materials: Strong oxidizers.
Hazardous Decomposition Products: Carbon oxides (CO, CO2).
SECTION 11: TOXICOLOGICAL INFORMATION
Information on Toxicological Effects - Product
LD50 and LC50 Data: Not available
Skin Corrosion/Irritation: Causes skin irritation.
Serious Eye Damage/Irritation: Causes serious eye irritation.
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Teratogenicity: Not available
Carcinogenicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs through prolonged or repeated exposure.
Reproductive Toxicity: Suspected of damaging fertility or the unborn child.
Specific Target Organ Toxicity (Single Exposure): May cause drowsiness or dizziness.
Acute Toxicity: Not classified
HOLD
TM
SPRAY-ON TRAY ADHESIVE
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
11/11/2014 EN (English US) 8/12
Aspiration Hazard: May be fatal if swallowed and enters airways.
Symptoms/Injuries After Inhalation: Excessive exposure may cause central nervous system effects may include headache, dizziness,
loss of balance and coordination, unconsciousness, coma, respiratory failure, and death. Asphyxiant gas, can be fatal. May cause
damage to the blood, central nervous system, and cardiovascular system. High concentrations of gas can cause unconciousness and
death. Has rotten egg smell but is not a good indicator of the presence of gas as olifactory fatigue (loss of smell) occurs rapidly. Being
under the influence of alcohol may enhance the effects of this product.
Symptoms/Injuries After Skin Contact: Causes skin irritation.
Symptoms/Injuries After Eye Contact: Causes serious eye irritation.
Symptoms/Injuries After Ingestion: The major health threat of ingestion occurs from the danger of aspiration(breathing) of liquid
drops into the lungs, particularly from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung
damage, respiratory failure and even death.
Chronic Symptoms: Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated
exposure.
Information on Toxicological Effects - Ingredient(s)
LD50 and LC50 Data:
Propane (74-98-6)
LC50 Inhalation Rat 658 mg/l/4h
Butane (106-97-8)
LC50 Inhalation Rat 30957 mg/m³ (Exposure time: 4 h)
Toluene (108-88-3)
LD50 Oral Rat 5580 mg/kg
LD50 Dermal Rabbit 12000 mg/kg
ATE US (vapors) 25.70 mg/l/4h
Isopropyl alcohol (67-63-0)
LD50 Oral Rat 4710 mg/kg
LD50 Dermal Rabbit 4059 mg/kg
LC50 Inhalation Rat 72600 mg/m³ (Exposure time: 4 h)
Toluene (108-88-3)
IARC Group 3
Isopropyl alcohol (67-63-0)
IARC Group 3
SECTION 12: ECOLOGICAL INFORMATION
Toxicity Not classified
Toluene (108-88-3)
LC50 Fish 1 15.22 - 19.05 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 5.46 - 9.83 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
LC 50 Fish 2 12.6 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
EC50 Daphnia 2 11.5 mg/l (Exposure time: 48 h - Species: Daphnia magna)
NOEC chronic crustacea 0.74 mg/l (Ceriodaphnia dubia)
Isopropyl alcohol (67-63-0)
LC50 Fish 1 9640 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 13299 mg/l (Exposure time: 48 h - Species: Daphnia magna)
EC50 Other Aquatic Organisms 1 1000 mg/l (Exposure time: 96 h - Species: Desmodesmus subspicatus)
LC 50 Fish 2 11130 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
EC50 Other Aquatic Organisms 2 1000 mg/l (Exposure time: 72 h - Species: Desmodesmus subspicatus)
Persistence and Degradability Not established
Bioaccumulative Potential
HOLD
TM
SPRAY-ON TRAY ADHESIVE
Bioaccumulative Potential Not established.
HOLD
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SPRAY-ON TRAY ADHESIVE
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
11/11/2014 EN (English US) 9/12
Propane (74-98-6)
Log Pow 2.3
Butane (106-97-8)
Log Pow 2.89
Toluene (108-88-3)
Log Pow 2.65
Isopropyl alcohol (67-63-0)
Log Pow 0.05 (at 25 °C)
Mobility in Soil Not available
Other Adverse Effects
Other Information: Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial
and international regulations.
Additional Information: Flammable vapors may accumulate in the container. Container under pressure. Do not drill or burn even
after use.
Ecology – Waste Materials: Hazardous waste due to toxicity.
SECTION 14: TRANSPORT INFORMATION
Please see current shipping paper for most up to date shipping information including exemptions and special circumstances.
In Accordance with DOT
Proper Shipping Name : AEROSOLS flammable, (each not exceeding 1 L capacity)
Hazard Class : 2.1
Identification Number : UN1950
Label Codes : 2.1
ERG Number : 126/171
In Accordance with IMDG
Proper Shipping Name : AEROSOLS
Hazard Class : 2
Identification Number : UN1950
Label Codes : 2.1
EmS-No. (Fire) : F-D
EmS-No. (Spillage) : S-U
In Accordance with IATA
Proper Shipping Name : AEROSOLS, FLAMMABLE
Identification Number : UN1950
Hazard Class : 2
Label Codes : 2.1
ERG Code (IATA) : 10L
In Accordance with TDG
Proper Shipping Name : AEROSOLS, flammable
Hazard Class : 2.1
Identification Number : 1950
Label Codes : 2.1
SECTION 15: REGULATORY INFORMATION
US Federal Regulations
HOLD
TM
SPRAY-ON TRAY ADHESIVE
SARA Section 311/312 Hazard Classes Sudden release of pressure hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Fire hazard
HOLD
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SPRAY-ON TRAY ADHESIVE
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
11/11/2014 EN (English US) 10/12
Propane (74-98-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Butane (106-97-8)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Toluene (108-88-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on United States SARA Section 313
RQ (Reportable Quantity, Section 304 of EPA's List of Lists): 1000 lb
SARA Section 313 - Emission Reporting 1.0 %
Isopropyl alcohol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on United States SARA Section 313
EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA.
SARA Section 313 - Emission Reporting 1.0 % (only if manufactured by the strong acid process, no supplier notification)
US State Regulations
Toluene (108-88-3)
U.S. - California - Proposition 65 - Developmental Toxicity WARNING: This product contains chemicals known to the State of
California to cause birth defects.
U.S. - California - Proposition 65 - Reproductive Toxicity Female
WARNING: This product contains chemicals known to the State of
California to cause (Female) reproductive harm.
Propane (74-98-6)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
Butane (106-97-8)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
Toluene (108-88-3)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
Isopropyl alcohol (67-63-0)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
Canadian Regulations
Propane (74-98-6)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification Class A - Compressed Gas
HOLD
TM
SPRAY-ON TRAY ADHESIVE
WHMIS Classification Class B Division 5 - Flammable Aerosol
Class D Division 2 Subdivision A - Very toxic material causing other toxic effects
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
HOLD
TM
SPRAY-ON TRAY ADHESIVE
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
11/11/2014 EN (English US) 11/12
Class B Division 1 - Flammable Gas
Butane (106-97-8)
Listed on the Canadian DSL (Domestic Substances List)
Listed on the Canadian IDL (Ingredient Disclosure List)
IDL Concentration 1 %
WHMIS Classification Class A - Compressed Gas
Class B Division 1 - Flammable Gas
Toluene (108-88-3)
Listed on the Canadian DSL (Domestic Substances List)
Listed on the Canadian IDL (Ingredient Disclosure List)
IDL Concentration 1 %
WHMIS Classification Class B Division 2 - Flammable Liquid
Class D Division 2 Subdivision A - Very toxic material causing other toxic effects
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects
Isopropyl alcohol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
Listed on the Canadian IDL (Ingredient Disclosure List)
IDL Concentration 1 %
WHMIS Classification Class B Division 2 - Flammable Liquid
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS
contains all of the information required by CPR.
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision Date : 11/11/2014
Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA
Hazard Communication Standard 29 CFR 1910.1200.
GHS Full Text Phrases:
------ Aquatic Acute 2 Hazardous to the aquatic environment - Acute Hazard Category 2
------ Aquatic Chronic 3 Hazardous to the aquatic environment - Chronic Hazard Category 3
------ Asp. Tox. 1 Aspiration hazard Category 1
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ Flam. Aerosol 1 Flammable aerosol Category 1
------ Flam. Gas 1 Flammable gases Category 1
------ Flam. Liq. 2 Flammable liquids Category 2
------ Liquefied gas Gases under pressure Liquefied gas
------ Repr. 2 Reproductive toxicity Category 2
------ Simple Asphy Simple Asphyxiant
------ Skin Irrit. 2 Skin corrosion/irritation Category 2
------ STOT RE 2 Specific target organ toxicity (repeated exposure) Category 2
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ H220 Extremely flammable gas
------ H222 Extremely flammable aerosol
------ H225 Highly flammable liquid and vapor
------ H280 Contains gas under pressure; may explode if heated
------ H304 May be fatal if swallowed and enters airways
------ H315 Causes skin irritation
------ H319 Causes serious eye irritation
------ H336 May cause drowsiness or dizziness
HOLD
TM
SPRAY-ON TRAY ADHESIVE
Safety Data Sheet
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations
11/11/2014 EN (English US) 12/12
------ H361 Suspected of damaging fertility or the unborn child
------ H373 May cause damage to organs through prolonged or repeated exposure
------ H401 Toxic to aquatic life
------ H412 Harmful to aquatic life with long lasting effects
Party Responsible for the Preparation of This Document
Water Pik, Inc.
Telephone: 800-525-2020
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and
environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
North America GHS US 2012 & WHMIS 2

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