Safety Data Sheet SsssSSherrSheetSSh - Dyno Nobel

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SDS# 1026 Date: 05/05/2015 Page 1 of 12
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SECTION 1 – IDENTIFICATION
Name, Address, and Telephone of the Responsible Party
Dyno Nobel Inc.
2795 East Cottonwood Parkway, Suite 500
Salt Lake City, Utah 84121
Phone: 801-364-4800 Fax 801-321-6703
E-Mail: dnna.hse@am.dynonobel.com www.dynonobel.com
SDS #: 1026
Date: 05/05/2015
Supersedes: 12/20/2012
Product Identifier
Product Form: Mixture
Product Name: Mixed Acid
Other Means of Identification
Product Class: Nitrating Acid
Intended Use of the Product
Industrial applications
Emergency Telephone Number
FOR 24 HOUR EMERGENCY, CALL CHEMTREC (USA) 800-424-9300
CANUTEC (CANADA) 613-996-6666
SECTION 2 – HAZARD(S) IDENTIFICATION
Classification of the Substance or Mixture
Classification (GHS-US)
Ox. Liq. 3 H272
Met. Corr. 1 H290
Skin Corr. 1A H314
Eye Dam. 1 H318
Aquatic Acute 3 H402
Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) :
GHS03 GHS05
Signal Word (GHS-US) : Danger
Hazard Statements (GHS-US) : H272 - May intensify fire; oxidizer
H290 - May be corrosive to metals
H314 - Causes severe skin burns and eye damage
H318 - Causes serious eye damage
H402 - Harmful to aquatic life
Precautionary Statements (GHS-US) : P210 - Keep away from open flames, heat, sparks, hot surfaces. - No
smoking.
P220 - Keep/Store away from combustible materials.
P221 - Take any precaution to avoid mixing with combustible materials.
P234 - Keep only in original container.
P260 - Do not breathe mist, spray, vapors.
P264 - Wash hands, forearms and exposed areas thoroughly after handling.
P273 - Avoid release to the environment.
P280 - Wear eye protection, protective clothing, protective gloves, face
shield.
P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce
vomiting.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
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P304+P340 - IF INHALED: Remove person to fresh air and keep at rest in a
position comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER or doctor/physician.
P321 - Specific treatment (see Section 4).
P363 - Wash contaminated clothing before reuse.
P370+P378 - In case of fire: Use appropriate media to extinguish.
P390 - Absorb spillage to prevent material damage.
P405 - Store locked up.
P406 - Store in corrosive resistant container with a resistant inner liner.
P501 - Dispose of contents/container according to local, regional, national,
territorial, provincial, and international regulations.
Other Hazards
Hazards Not Otherwise Classified (HNOC): When diluting, always add acid to water and not water to acid. Exposure
may aggravate those with pre-existing eye, skin, or respiratory conditions.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
Mixture
Name Product identifier % (w/w) Ingredient Classification (GHS-US)
Sulfuric acid (CAS No) 7664-93-9 15 - 40,
40 - 70,
60 - 100
Met. Corr. 1, H290
Skin Corr. 1A, H314
Eye Dam. 1, H318
Aquatic Acute 3, H402
Nitric acid (CAS No) 7697-37-2 15 - 40,
40 - 70,
60 - 100
Ox. Liq. 3, H272
Met. Corr. 1, H290
Skin Corr. 1A, H314
Eye Dam. 1, H318
Multiple WHMIS ranges have been utilized due to varying composition.
Full text of H-phrases: see section 16
Ingredients, other than those mentioned above, as used in this product are not hazardous as defined under
current Department of Labor regulations, or are present in deminimus concentrations (less than 0.1% for
carcinogens, less than 1.0% for other hazardous materials).
SECTION 4 - FIRST AID MEASURES
Description of First Aid Measures
General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label
where possible).
Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. If exposed seek immediate
medical attention.
Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 60 minutes. If exposed seek
immediate medical attention.
Eye Contact: Rinse cautiously with water for at least 60 minutes. Seek immediate medical attention.l
Ingestion: Rinse mouth. Do NOT induce vomiting. If ingested seek immediate medical attention.
Most Important Symptoms and Effects Both Acute and Delayed
General: Causes severe skin burns and eye damage. Effects of exposure (inhalation, ingestion or skin contact) to
substance may be delayed.
Inhalation: Inhalation may cause immediate severe irritation progressing quickly to chemical burns.
Skin Contact: Causes serious burns.
Eye Contact: Causes serious eye damage.
Ingestion: Ingestion is likely to be harmful or have adverse effects.
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Chronic Symptoms: None expected under normal conditions of use.
Indication of Any Immediate Medical Attention and Special Treatment Needed
If exposed, seek medical attention.
SECTION 5 - FIRE-FIGHTING MEASURES
Extinguishing Media
Use water spray to cool non-leaking fire-exposed containers and to reduce and knock down vapors. Do not use solid
water streams near ruptured tanks or spills of sulfuric acid. Acid reacts violently with water and can splatter acid on
personnel. Apply water from as far away as possible and avoid directing water into the acid. Neutralize small amounts of
spilled acid with crushed limestone, soda ash or lime. Wear self-contained breathing apparatus and full fire fighting
protective gear.
Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Unsuitable Extinguishing Media: Do not use a heavy water stream. A heavy water stream may spread burning liquid.
Special Hazards Arising From the Substance or Mixture
Will emit oxides of nitrogen and sulfur upon heating. Strong oxidizer. May cause spontaneous combustion when in
contact with organic or combustible materials. Reacts vigorously with water to liberate heat, oxides of nitrogen and sulfur
and acid fumes.
Fire Hazard: Not flammable but will support combustion. May intensify fire; oxidizer.
Explosion Hazard: Risk of explosion in contact with reducing agents.
Reactivity: Contact with metals may evolve flammable hydrogen gas. Violent exothermic reaction with water (moisture):
release of corrosive gases/vapors.
Reference to Other Sections: Refer to section 9 for flammability properties.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Avoid all contact with skin, eyes, or clothing. Avoid breathing vapor, mist, or spray. Gas/vapor is
heavier than air. May accumulate in confined spaces, particularly at or below ground level.
For Non-Emergency Personnel
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
For Emergency Personnel
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Stop leak if safe to do so. Eliminate ignition sources. Ventilate area.
Environmental Precautions
Prevent entry to sewers and public waters.
Methods and Material for Containment and Cleaning Up
For Containment: Absorb and/or contain spill with inert material, then place in suitable container. Do not take up in
combustible material such as saw dust or cellulosic material.
Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely. Cautiously neutralize spilled liquid.
Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection
SECTION 7 - HANDLING AND STORAGE
Precautions for Safe Handling
Additional Hazards When Processed: May be corrosive to metals.
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and
forearms thoroughly after handling. Do not eat, drink or smoke when using this product.
Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Comply with applicable regulations.
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Storage Conditions: Store in a dry, cool and well-ventilated place. Keep/Store away from direct sunlight, extremely high
or low temperatures and incompatible materials. Keep container closed when not in use. Keep in fireproof place.
Incompatible Materials: Strong acids. Strong bases. Strong oxidizers.
Special Rules on Packaging: Store in original container or corrosive resistant and/or lined container.
Specific End Use(s)
Industrial applications
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters
Nitric acid (7697-37-2)
Mexico OEL TWA (mg/m³) 5 mg/m³
Mexico OEL TWA (ppm) 2 ppm
Mexico OEL STEL (mg/m³) 10 mg/m³
Mexico OEL STEL (ppm) 4 ppm
USA ACGIH ACGIH TWA (ppm) 2 ppm
USA ACGIH ACGIH STEL (ppm) 4 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 2 ppm
USA NIOSH NIOSH REL (TWA) (mg/m³) 5 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 2 ppm
USA NIOSH NIOSH REL (STEL) (mg/m³) 10 mg/m³
USA NIOSH NIOSH REL (STEL) (ppm) 4 ppm
USA IDLH US IDLH (ppm) 25 ppm
Alberta OEL STEL (mg/m³) 10 mg/m³
Alberta OEL STEL (ppm) 4 ppm
Alberta OEL TWA (mg/m³) 5.2 mg/m³
Alberta OEL TWA (ppm) 2 ppm
British Columbia OEL STEL (ppm) 4 ppm
British Columbia OEL TWA (ppm) 2 ppm
Manitoba OEL STEL (ppm) 4 ppm
Manitoba OEL TWA (ppm) 2 ppm
New Brunswick OEL STEL (mg/m³) 10 mg/m³
New Brunswick OEL STEL (ppm) 4 ppm
New Brunswick OEL TWA (mg/m³) 5.2 mg/m³
New Brunswick OEL TWA (ppm) 2 ppm
Newfoundland &
Labrador
OEL STEL (ppm) 4 ppm
Newfoundland &
Labrador
OEL TWA (ppm) 2 ppm
Nova Scotia OEL STEL (ppm) 4 ppm
Nova Scotia OEL TWA (ppm) 2 ppm
Nunavut OEL STEL (mg/m³) 10 mg/m³
Nunavut OEL STEL (ppm) 4 ppm
Nunavut OEL TWA (mg/m³) 5.2 mg/m³
Nunavut OEL TWA (ppm) 2 ppm
Northwest Territories OEL STEL (mg/m³) 10 mg/m³
Northwest Territories OEL STEL (ppm) 4 ppm
Northwest Territories OEL TWA (mg/m³) 5.2 mg/m³
Northwest Territories OEL TWA (ppm) 2 ppm
Ontario OEL STEL (ppm) 4 ppm
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Ontario OEL TWA (ppm) 2 ppm
Prince Edward Island OEL STEL (ppm) 4 ppm
Prince Edward Island OEL TWA (ppm) 2 ppm
Québec VECD (mg/m³) 10 mg/m³
Québec VECD (ppm) 4 ppm
Québec VEMP (mg/m³) 5.2 mg/m³
Québec VEMP (ppm) 2 ppm
Saskatchewan OEL STEL (ppm) 4 ppm
Saskatchewan OEL TWA (ppm) 2 ppm
Yukon OEL STEL (mg/m³) 10 mg/m³
Yukon OEL STEL (ppm) 4 ppm
Yukon OEL TWA (mg/m³) 5 mg/m³
Yukon OEL TWA (ppm) 2 ppm
Sulfuric acid (7664-93-9)
Mexico OEL TWA (mg/m³) 1 mg/m³
USA ACGIH ACGIH TWA (mg/m³) 0.2 mg/m³
USA OSHA OSHA PEL (TWA) (mg/m³) 1 mg/m³
USA NIOSH NIOSH REL (TWA) (mg/m³) 1 mg/m³
USA IDLH US IDLH (mg/m³) 15 mg/m³
Alberta OEL STEL (mg/m³) 3 mg/m³
Alberta OEL TWA (mg/m³) 1 mg/m³
British Columbia OEL TWA (mg/m³) 0.2 mg/m³ (Thoracic, contained in strong inorganic
acid mists)
Manitoba OEL TWA (mg/m³) 0.2 mg/m³
New Brunswick OEL STEL (mg/m³) 3 mg/m³
New Brunswick OEL TWA (mg/m³) 1 mg/m³
Newfoundland &
Labrador
OEL TWA (mg/m³) 0.2 mg/m³
Nova Scotia OEL TWA (mg/m³) 0.2 mg/m³
Nunavut OEL STEL (mg/m³) 3 mg/m³
Nunavut OEL TWA (mg/m³) 1 mg/m³
Northwest Territories OEL STEL (mg/m³) 3 mg/m³
Northwest Territories OEL TWA (mg/m³) 1 mg/m³
Ontario OEL TWA (mg/m³) 0.2 mg/m³
Prince Edward Island OEL TWA (mg/m³) 0.2 mg/m³
Québec VECD (mg/m³) 3 mg/m³
Québec VEMP (mg/m³) 1 mg/m³
Saskatchewan OEL STEL (mg/m³) 0.6 mg/m³
Saskatchewan OEL TWA (mg/m³) 0.2 mg/m³
Yukon OEL STEL (mg/m³) 1 mg/m³
Yukon OEL TWA (mg/m³) 1 mg/m³
Exposure Controls
Appropriate Engineering Controls: Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Mechanical
ventilation and/or local exhaust is indicated where needed to meet TLV requirement.
Personal Protective Equipment: Protective goggles. Face shield. Gloves. Protective clothing. Insufficient ventilation:
wear respiratory protection.
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SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Information on Basic Physical and Chemical Properties
Physical State : Liquid
Appearance : Colorless to light yellow, cloudy liquid
Odor : Acrid odor
Odor Threshold : Not available
pH : Not available
Relative Evaporation Rate (butylacetate=1) : < 1
Melting Point : Not available
Freezing Point : Not available
Boiling Point : 82 - 132 °C (180 - 270 °F)
Flash Point : Not available
Auto-ignition Temperature : Not available
Decomposition Temperature : Not available
Flammability (solid, gas) : Not available
Lower Flammable Limit : Not available
Upper Flammable Limit : Not available
Vapor Pressure : Not available
Relative Vapor Density at 20 °C : 2.5 - 3 (Air=1)
Relative Density : Not available
Density : 1.55 - 1.85 g/cc
Specific Gravity : Not available
Solubility : Complete in water
Partition coefficient: n-octanol/water : Not available
Viscosity : Not available
Explosion Data – Sensitivity to Mechanical
Impact
: Not expected to present an explosion hazard due to mechanical
impact.
Explosion Data – Sensitivity to Static
Discharge
: Not expected to present an explosion hazard due to static discharge.
Materials for Protective Clothing: Neoprene or vinyl gloves required and suitable body protection that provides acid
resistant protection against splash and skin contact.
Hand Protection: Wear chemically resistant protective gloves.
Eye Protection: Acid proof goggles and face shield should be required where acid is transferred, sampled, or where
persons are otherwise potentially exposed. Eye baths should be provided when direct contact is possible.
Skin and Body Protection: Neoprene or vinyl gloves should be worn. Where spill or splash potential exists, rubberized
aprons or chemical resistant suits are strongly recommended.
Respiratory Protection: For concentrations above the exposure limits, use full face supplied air respirator approved by
NIOSH for nitric acid, nitrogen oxide gases or mists, sulfuric acid, and sulfur oxides. Chemical cartridge or canister
respirators are not suitable for nitric acid or nitrogen oxide use.
Environmental Exposure Controls: Do not allow the product to be released into the environment.
Consumer Exposure Controls: Do not eat, drink or smoke during use
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SECTION 10 - STABILITY AND REACTIVITY
Reactivity: Contact with metals may evolve flammable hydrogen gas. Violent exothermic reaction with water
(moisture): release of corrosive gases/vapors.
Chemical Stability: Stable under recommended handling and storage conditions (see section 7).
Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Overheating. Open flame.
Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Metals. Organic materials. Chlorides.
Hazardous Decomposition Products: Nitrogen oxides. Sulfur oxides. Thermal decomposition generates corrosive
vapors.
SECTION 11 - TOXICOLOGICAL INFORMATION
Information on Toxicological Effects - Product
Acute Toxicity: Not classified
LD50 and LC50 Data: Not available
Skin Corrosion/Irritation: Causes severe skin burns and eye damage.
Serious Eye Damage/Irritation: Causes serious eye damage.
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Teratogenicity: Not classified
Carcinogenicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): Not classified
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: Inhalation may cause immediate severe irritation progressing quickly to chemical
burns.
Symptoms/Injuries After Skin Contact: Causes serious burns.
Symptoms/Injuries After Eye Contact: Causes serious eye damage.
Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects.
Chronic Symptoms: None expected under normal conditions of use.
Information on Toxicological Effects - Ingredient(s)
Sulfuric acid (7664-93-9)
LD50 Oral Rat 2140 mg/kg
LC50 Inhalation Rat 510 mg/m³ (Exposure time: 2 h)
Sulfuric acid (7664-93-9)
IARC Group 1
SECTION 12: ECOLOGICAL INFORMATION
Toxicity
Ecology - General: This material is hazardous to the aquatic environment. Keep out of sewers and waterways.
Ecology - Water: Harmful to aquatic life.
Sulfuric acid (7664-93-9)
LC50 Fish 1 500 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [static])
LC 50 Fish 2 42 mg/l (Exposure time: 96 h - Species: Gambusia affinis [static])
Persistence and Degradability Not available
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Bioaccumulative Potential
Nitric acid (7697-37-2)
Log Pow -2.3 (at 25 °C)
Sulfuric acid (7664-93-9)
BCF fish 1 (no bioaccumulation)
Mobility in Soil Not available
Other Adverse Effects
Other Information: Avoid release to the environment.
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national,
provincial, territorial and international regulations.
SECTION 14 - TRANSPORT INFORMATION
14.1 In Accordance with DOT
Proper Shipping Name : NITRATING ACID MIXTURES with >50% nitric acid
Hazard Class : 8
Identification Number : UN1796
Label Codes : 8,5.1
Packing Group : I (>50% Nitric Acid)
Packing Group : II (<50% Nitric Acid)
ERG Number : 157
14.2 In Accordance with IMDG
Proper Shipping Name : NITRATING ACID MIXTURE
Hazard Class : 8
Identification Number : UN1796
Packing Group : I
Label Codes : 8,5.1
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-Q
14.3 In Accordance with IATA
Proper Shipping Name : NITRATING ACID MIXTURE
Packing Group : I
Identification Number : UN1796
Hazard Class : 8
Label Codes : 8,5.1
ERG Code (IATA) : 8X
14.4 In Accordance with TDG
Proper Shipping Name : NITRATING ACID MIXTURE with >50% nitric acid
Packing Group : I
Hazard Class : 8
Identification Number : UN1796
Label Codes : 8,5.1
SECTION 15 - REGULATORY INFORMATION
US Federal Regulations
Mixed Acid
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Fire hazard
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Nitric acid (7697-37-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on SARA Section 302 (Specific toxic chemical listings)
Listed on SARA Section 313 (Specific toxic chemical listings)
SARA Section 302 Threshold Planning Quantity
(TPQ)
1000
SARA Section 313 - Emission Reporting 1.0 %
Sulfuric acid (7664-93-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on SARA Section 302 (Specific toxic chemical listings)
Listed on SARA Section 313 (Specific toxic chemical listings)
SARA Section 302 Threshold Planning Quantity
(TPQ)
1000
SARA Section 313 - Emission Reporting 1.0 % (acid aerosols including mists, vapors, gas, fog, and
other airborne forms of any particle size)
US State Regulations
Sulfuric acid (7664-93-9)
U.S. - California - Proposition 65 - Carcinogens List WARNING: This product contains chemicals known to the
State of California to cause cancer.
Nitric acid (7697-37-2)
U.S. - California - SCAQMD - Toxic Air Contaminants - Non-Cancer Acute
U.S. - California - SCAQMD - Toxic Air Contaminants With Proposed Risk Values
U.S. - California - Toxic Air Contaminant List (AB 1807, AB 2728)
U.S. - Connecticut - Hazardous Air Pollutants - HLVs (30 min)
U.S. - Connecticut - Hazardous Air Pollutants - HLVs (8 hr)
U.S. - Delaware - Accidental Release Prevention Regulations - Sufficient Quantities
U.S. - Delaware - Accidental Release Prevention Regulations - Threshold Quantities
U.S. - Delaware - Accidental Release Prevention Regulations - Toxic Endpoints
U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs)
U.S. - Idaho - Occupational Exposure Limits - TWAs
U.S. - Illinois - Toxic Air Contaminants
U.S. - Louisiana - Reportable Quantity List for Pollutants
U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 1
U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 2
U.S. - Massachusetts - Oil & Hazardous Material List - Reportable Quantity
U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 1
U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 2
RTK - U.S. - Massachusetts - Right To Know List
U.S. - Massachusetts - Toxics Use Reduction Act
U.S. - Michigan - Occupational Exposure Limits - STELs
U.S. - Michigan - Occupational Exposure Limits - TWAs
U.S. - Michigan - Polluting Materials List
U.S. - Michigan - Process Safety Management Highly Hazardous Chemicals
U.S. - Minnesota - Chemicals of High Concern
U.S. - Minnesota - Hazardous Substance List
U.S. - Minnesota - Permissible Exposure Limits - STELs
U.S. - Minnesota - Permissible Exposure Limits - TWAs
U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour
U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual
U.S. - New Jersey - Discharge Prevention - List of Hazardous Substances
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U.S. - New Jersey - Environmental Hazardous Substances List
RTK - U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - New Jersey - Special Health Hazards Substances List
U.S. - New Jersey - TCPA - Extraordinarily Hazardous Substances (EHS)
U.S. - New York - Occupational Exposure Limits - TWAs
U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances
U.S. - North Carolina - Control of Toxic Air Pollutants
U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 1-Hour
U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 8-Hour
U.S. - Ohio - Accidental Release Prevention - Threshold Quantities
U.S. - Ohio - Extremely Hazardous Substances - Threshold Quantities
U.S. - Oregon - Permissible Exposure Limits - TWAs
RTK - U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
RTK - U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - 1-Hour
U.S. - South Carolina - Toxic Air Pollutants - Maximum Allowable Concentrations
U.S. - South Carolina - Toxic Air Pollutants - Pollutant Categories
U.S. - Tennessee - Occupational Exposure Limits - STELs
U.S. - Tennessee - Occupational Exposure Limits - TWAs
U.S. - Texas - Effects Screening Levels - Long Term
U.S. - Texas - Effects Screening Levels - Short Term
U.S. - Vermont - Permissible Exposure Limits - STELs
U.S. - Vermont - Permissible Exposure Limits - TWAs
U.S. - Washington - Permissible Exposure Limits - STELs
U.S. - Washington - Permissible Exposure Limits - TWAs
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 25 Feet to Less Than 40
Feet
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 40 Feet to Less Than 75
Feet
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 75 Feet or Greater
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights Less Than 25 Feet
U.S. - Wyoming - Process Safety Management - Highly Hazardous Chemicals
Sulfuric acid (7664-93-9)
Strong inorganic acid mists containing sulfuric acid are present on the State of California list of Chemicals Known to the
State to Cause Cancer or Reproductive Toxicity (Cal Prop 65).
U.S. - California - SCAQMD - Toxic Air Contaminants - Non-Cancer Acute
U.S. - California - SCAQMD - Toxic Air Contaminants - Non-Cancer Chronic
U.S. - California - Toxic Air Contaminant List (AB 1807, AB 2728)
U.S. - Connecticut - Hazardous Air Pollutants - HLVs (30 min)
U.S. - Connecticut - Hazardous Air Pollutants - HLVs (8 hr)
U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations
U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs)
U.S. - Idaho - Occupational Exposure Limits - TWAs
U.S. - Illinois - Toxic Air Contaminant Carcinogens
U.S. - Illinois - Toxic Air Contaminants
U.S. - Louisiana - Reportable Quantity List for Pollutants
U.S. - Maine - Air Pollutants - Hazardous Air Pollutants
U.S. - Massachusetts - Allowable Ambient Limits (AALs)
U.S. - Massachusetts - Allowable Threshold Concentrations (ATCs)
U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 1
U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 2
U.S. - Massachusetts - Oil & Hazardous Material List - Reportable Quantity
SDS# 1026 Date: 05/05/2015 Page 11 of 12
Safety Data Sheet
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U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 1
U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 2
RTK - U.S. - Massachusetts - Right To Know List
U.S. - Massachusetts - Threshold Effects Exposure Limits (TELs)
U.S. - Massachusetts - Toxics Use Reduction Act
U.S. - Michigan - Occupational Exposure Limits - TWAs
U.S. - Michigan - Polluting Materials List
U.S. - Minnesota - Chemicals of High Concern
U.S. - Minnesota - Hazardous Substance List
U.S. - Minnesota - Permissible Exposure Limits - TWAs
U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour
U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual
U.S. - New Jersey - Discharge Prevention - List of Hazardous Substances
U.S. - New Jersey - Environmental Hazardous Substances List
RTK - U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - New Jersey - Special Health Hazards Substances List
U.S. - New York - Occupational Exposure Limits - TWAs
U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances
U.S. - North Carolina - Control of Toxic Air Pollutants
U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 8-Hour
U.S. - Ohio - Extremely Hazardous Substances - Threshold Quantities
U.S. - Oregon - Permissible Exposure Limits - TWAs
RTK - U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
RTK - U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - 1-Hour
U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - Annual
U.S. - South Carolina - Toxic Air Pollutants - Maximum Allowable Concentrations
U.S. - South Carolina - Toxic Air Pollutants - Pollutant Categories
U.S. - Tennessee - Occupational Exposure Limits - TWAs
U.S. - Texas - Effects Screening Levels - Long Term
U.S. - Texas - Effects Screening Levels - Short Term
U.S. - Vermont - Permissible Exposure Limits - TWAs
U.S. - Washington - Permissible Exposure Limits - STELs
U.S. - Washington - Permissible Exposure Limits - TWAs
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 25 Feet to Less Than 40
Feet
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 40 Feet to Less Than 75
Feet
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 75 Feet or Greater
U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights Less Than 25 Feet
Canadian Regulations
Mixed Acid
WHMIS Classification Class C - Oxidizing Material
Class E - Corrosive Material
Nitric acid (7697-37-2)
Listed on the Canadian DSL (Domestic Substances List) inventory.
Listed on the Canadian Ingredient Disclosure List
SDS# 1026 Date: 05/05/2015 Page 12 of 12
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Disclaimer
Dyno Nobel Inc. and its subsidiaries disclaim any warranties with respect to this product, the safety or suitability thereof, the information contained
herein, or the results to be obtained, whether express or implied, INCLUDING WITHOUT LIMITATION, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE AND/OR OTHER WARRANTY. The information contained herein is provided for
reference purposes only and is intended only for persons having relevant technical skills. Because conditions and manner of use are outside of our
control, the user is responsible for determining the conditions of safe use of the product. Buyers and users assume all risk, responsibility and liability
whatsoever from any and all injuries (including death), losses, or damages to persons or property arising from the use of this product or information.
Under no circumstances shall either Dyno Nobel Inc. or any of its subsidiaries be liable for special, consequential or incidental damages or for
anticipated loss of profits.
Dyno Nobel SDS
WHMIS Classification Class C - Oxidizing Material
Class E - Corrosive Material
Sulfuric acid (7664-93-9)
Listed on the Canadian DSL (Domestic Substances List) inventory.
Listed on the Canadian Ingredient Disclosure List
WHMIS Classification Class E - Corrosive Material
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the SDS contains all of the information required by CPR.
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision date : 05/05/2015
Other Information : This document has been prepared in accordance with the SDS requirements of the
OSHA Hazard Communication Standard 29 CFR 1910.1200.
GHS Full Text Phrases:
Aquatic Acute 3 Hazardous to the aquatic environment - Acute Hazard Category 3
Eye Dam. 1 Serious eye damage/eye irritation Category 1
Met. Corr. 1 Corrosive to metals Category 1
Ox. Liq. 3 Oxidizing liquids Category 3
Skin Corr. 1A Skin corrosion/irritation Category 1A
H272 May intensify fire; oxidizer
H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H402 Harmful to aquatic life
NFPA Health Hazard : 3 - Short exposure could cause serious temporary or
residual injury even though prompt medical attention
was given.
NFPA Fire Hazard : 0 - Materials that will not burn.
NFPA Reactivity
NFPA Specific Hazard
:
:
1 - Normally stable, but can become unstable at
elevated temperatures and pressures or may react
with water with some release of energy, but not
violently.
OX - This denotes an oxidizer, a chemical which can
greatly increase the rate of combustion/fire.
Party Responsible for the Preparation of This Document
Dyno Nobel Inc.
2795 East Cottonwood Parkway, Suite 500
Salt Lake City, Utah 84121
Phone: 801-364-4800

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