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MATERIAL SAFETY DATA SHEET
Page 1 of 8
4875B
IC3018-0101MSDS #:
Product Code:
Canon Ink Tank PGI-29YProduct Name:
4875BProduct Code:
Canon Inc.Manufacturer:
30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo 146-8501, JapanAddress:
Ink for Ink Jet PrinterRelevant Identified Uses:
SECTION 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
Ink tank containing yellow liquid ink with slight odor.
Emergency Overview:
SECTION 2 HAZARDS IDENTIFICATION
Not classified as dangerous.
EU Classification under 1999/45/EC:
Product Identifier:
Details of Supplier of Safety Data Sheet:
Supplier:
Address:
Telephone Number:
E-mail Address:
Emergency Telephone Number:
US Regulatory Status
Not classified as hazardous.
Not required
US Label Elements
Signal Word:
Not requiredHazard Warning:
Not requiredHazardous Component:
Not requiredSafety Advice:
under FHSA:
Not requiredSymbol & Indication:
Not requiredR-Phrase:
Not requiredDangerous Component:
EU Label Elements under 1999/45/EC:
Not requiredS-Phrase:
Not required
Applicable Label Elements in accordance with Annex V to 1999/45/EC:
Other Hazards:
None
under FHSA:
Revision Date:December 15, 2010Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 2 of 8
4875B
IC3018-0101MSDS #:
Product Code:
Carcinogen(s):
No component of this ink is listed as a human carcinogen or a potential carcinogen in IARC Monographs, NTP, OSHA regulations or Part 3 of
Annex VI to Regulation (EC) No 1272/2008.
Ingredient(s):
COMPOSITION/INFORMATION ON INGREDIENTSSECTION 3
Chemical Name/
Generic Name
CAS #/
EC #
Concentration/
Concentration
Range (%)
EU Classification according to
67/548/EEC
EU Classification according to
(EC) No 1272/2008
Note to
Other
Hazards*2Symbol/
Indication of Danger
R-Phrase*1 Hazard Class/
Category Code
Hazard
Statement*1
Glycerin
Triethylene glycol
Lactam
Water
56-81-5 /
200-289-5
112-27-6 /
203-953-2
Confidential
7732-18-5 /
231-791-2
5 - 10
5 - 10
5 - 10
60 - 80
None
None
None
None
None
None
None
None
None
None
None
None
None
None
None
None
(1)
(1)
*1 Full texts of R-phrase(s) and Hazard statement(s) are listed in SECTION 16
*2 The following substance(s) is (are) marked with (1), (2) and/or (3)
(1) Substance for which Occupational Exposure Limit(s) is (are) established (See SECTION 8)
(2) PBT substance or vPvB substance under Regulation (EC) No 1907/2006
(3) Substance listed in Candidate List of SVHC for Authorisation under Regulation (EC) No 1907/2006
Substance or Mixture: Mixture
Revision Date:December 15, 2010Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 3 of 8
4875B
IC3018-0101MSDS #:
Product Code:
CO2, water, foam or dry chemicals
Suitable Extinguishing Media:
None
Special Hazards:
CO, CO2, NOx and SOx
Hazardous Combustion Products:
Advice for Fire-fighters:
Avoid contact with skin, eyes and clothing.
Personal Precautions, Protective Equipment and Emergency Procedures:
Do not release to sewer, surface water or ground water.
Environmental Precautions:
Wipe off with wet cloth or paper.
Methods and Material for Containment and Cleaning Up:
Extinguishing Media:
Unsuitable Extinguishing Media:
None
SECTION 6 ACCIDENTAL RELEASE MEASURES
SECTION 5 FIRE FIGHTING MEASURES
If symptoms are experienced, move victim to fresh air and obtain medical advice.
Inhalation:
Rinse mouth. Give one or two glasses of water.
If irritation or discomfort occurs, obtain medical advice immediately.
Ingestion:
Immediately flush with lukewarm, gently flowing water for 5 minutes or until the chemical is removed.
If irritation persists, obtain medical advice immediately.
Eye:
Indication of Any Immediate Medical Attention and Special Treatment Needed:
First Aid Measures:
SECTION 4 FIRST AID MEASURES
None
Skin:
Wash with water and soap or mild detergent.
If irritation persists, obtain medical advice.
May cause minimal irritation. (See SECTION 11)
Eye:
Neither irritation nor sensitization is expected. (See SECTION 11)
Skin:
No adverse effects are expected under intended use.
Over exposure to vapor or mist may cause respiratory tract irritation, cough, dizziness, drowsiness, headache
and nausea.
Inhalation:
May cause abdominal pain, diarrhea, dizziness, drowsiness, dullness, headache, nausea and vomiting.
Ingestion:
Not identified
Chronic Effects:
Most Important Symptoms and Effects, both Acute and Delayed:
None
Revision Date:December 15, 2010Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 4 of 8
4875B
IC3018-0101MSDS #:
Product Code:
Use with adequate ventilation.
Avoid contact with skin, eyes and clothing.
In case of contact, wash out the contaminated area immediately.
Precautions for Safe Handling:
Keep in a cool and dry place.
Protect from sunlight.
Keep out of the reach of children.
Conditions for Safe Storage, Including Any Incompatibilities:
Control Parameters:
No special ventilation equipment is needed under intended use of this product.Engineering Controls:
Required Not RequiredRespiratory Protection:
Required Not RequiredEye/Face Protection:
Required Not Required
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Skin Protection:
Individual Protection Measures:
Ink for Ink Jet Printer.
For more information, please refer to the instruction of this product.
Specific End Uses:
SECTION 7 HANDLING AND STORAGE
USA
OSHA PEL
ACGIH TLV EU OEL DFG MAK
Product (Ink) Not established Not establishedNot established Not established
Glycerin mist:
TWA 15 mg/m3
(Total dust)
TWA 5 mg/m3
(Respirable fraction)
Not established
Glycerin mist:
TWA 10 mg/m3
Not established
Not established
Not established
Not established
1000 mg/m3
Glycerin
Triethylene glycol
Exposure Controls:
Revision Date:December 15, 2010Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 5 of 8
4875B
IC3018-0101MSDS #:
Product Code:
Slight odorOdor:
8 - 9pH:
Not available
Initial Boiling Point and
Boiling Range (°C):
Not availableMelting Point/Freezing Point (°C):
Not availableVapor Pressure :
Not availableVapor Density :
1.0 - 1.1Relative Density:
MiscibleWater Solubility :
Not availableFat Solubility :
Partition Coefficient (n-Octanol/Water):
Not availableEvaporation Rate:
Stable UnstableChemical Stability:
NoneConditions to Avoid:
Acids, bases, oxidizing materials and reducing agentsIncompatible Materials:
CO, CO2, NOx, SOx and AmmoniaHazardous Decomposition Products:
Possibility of Hazardous Reactions:
Appearance:
None (Estimate)Flash Point(°C):
None (Estimate)Explosive Properties:
None (Estimate)Oxidizing Properties:
Yellow liquid
Flammability: Neither flammable nor combustible.
Not availableDecomposition Temperature(°C):
Not available
Upper/Lower Flammable or
Explosive Limits:
Not availableAuto-ignition Temperature (°C):
Not available
1 - 5Viscosity (mPa s):
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
SECTION 10 STABILITY AND REACTIVITY
Information on Basic Physical and Chemical Properties:
Not availableOther Information:
Reactivity: None
None
Revision Date:December 15, 2010Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 6 of 8
4875B
IC3018-0101MSDS #:
Product Code:
Not available
Inhalation:
Not available
Ingestion:
Non-irritant (rabbit)
OECD Guidelines No. 404 (2002), (EC) No 440/2008 Method B4
Skin:
Minimal irritant (rabbit)
OECD Guidelines No. 405 (2002), (EC) No 440/2008 Method B5
Eye:
Non-sensitizer (mouse)
OECD Guidelines No. 429 (2002), (EC) No 440/2008 Method B42
Sensitization:
Ames test: Negative (S. typhimurium & E. Coli)
Mutagenicity:
Not available
Toxicity for Reproduction:
Not available
Carcinogenicity:
Not available
Other Information:
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity:
Information on Toxicological Effects:
Corrosivity/Irritation:
Skin:
Repeated Dose Toxicity:
Not available
Revision Date:December 15, 2010Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 7 of 8
4875B
IC3018-0101MSDS #:
Product Code:
Not availableMobility in Soil:
Not availablePersistence and Degradability:
Not availableBioaccumulative Potential:
Not availableToxicity:
Not availableOther Adverse Effects:
Disposal should be subject to federal, state and local laws.
Waste Treatment Methods:
None
SARA Title III §313:
None
California Proposition 65:
SECTION 13 DISPOSAL CONSIDERATIONS
< USA Information >
Chemical Name Weight %
Chemical Name Weight %
None
Safety, Health and Environmental Regulations/Legislation:
Not regulatedRestriction:
Not regulated(EC) No 1005/2009:
Not regulated(EC) No 689/2008:
< EU Information >
Others:
NoneUN Number:
NoneUN Proper Shipping Name:
NoneTransport Hazard Class:
NoneSpecial Precautions for User:
NonePacking Group:
Environmental Hazards:
SECTION 15 REGULATORY INFORMATION
Not applicable (Manufactured article)WHMIS Controlled Product:
Not classified as hazardous according to criteria of NOHSC.Statement of Hazardous Nature:
< Canada Information >
< Australia Information >
SECTION 12 ECOLOGICAL INFORMATION
SECTION 14 TRANSPORT INFORMATION
Others: This product contains a chemical substance which is being introduced under a Low Volume
Chemical Permit granted under section 21U(2) of the Industrial Chemicals (Notification and
Assessment) Act 1989.
Results of PBT and vPvB
Assessment:
No results that the component(s) of this ink meet(s) the PBT or vPvB criteria under
Regulation (EC) No 1907/2006.
Not classified as environmentally hazardous under UN Model Regulations and marine
pollutant under IMDG Code.
(EC) No 1907/2006: Not regulatedAuthorisation:
Not regulated(EC) No 850/2004:
Chemical Safety Assessment under (EC) No 1907/2006: Not required
Revision Date:December 15, 2010Date of Issue:
MATERIAL SAFETY DATA SHEET
Page 8 of 8
4875B
IC3018-0101MSDS #:
Product Code:
Literature References:

Estimate: Estimate based on data of similar product or the ingredient(s) of this product.
The information, data and recommendations set forth herein (the "Information") are presented in good faith and are believed to be correct as
of the date hereof. The company/manufacturer makes no representations as to the completeness or accuracy of the Information and disclaims
responsibility for any reliance thereon. The Information is provided upon the condition that the persons receiving same will make their own
determination as to its suitability for their purposes prior to use. Any use of the Information must be determined by the user to be in
accordance with applicable Federal, state and local laws and regulations. In no event will the company/manufacturer be responsible for
damages of any nature whatsoever resulting from the use or reliance upon the Information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION OR THE
PRODUCT TO WHICH THE INFORMATION REFERS.
SECTION 16 OTHER INFORMATION
- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environmental Protection Agency, 40CFR Part 372
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens
- World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of
Chemicals to Humans
- DFG, List of MAK and BAT Values
- EU Directive 1999/45/EC
- EU Regulation (EC) No 1907/2006, (EC) No 1272/2008, (EC) No 1005/2009, (EC) No 850/2004, (EC) No 689/2008
- Canada Workplace Hazardous Materials Information System
- Australia National Occupational Health and Safety Commission's Approved Criteria for Classifying Hazardous Substance [NOHSC:1008]
OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA)
FHSA: Federal Hazardous Substances Act (USA)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
SVHC: Substances of Very High Concern
IARC: International Agency for Research on Cancer
NTP: National Toxicology Program (USA)
OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA)
ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists
EU OEL: Occupational exposure limits at Community level under Directive 2004/37/EC, 98/24/EC, 91/322/EEC, 2000/39/EC, 2006/15/EC and
2009/161/EU
DFG MAK: MAK(Maximale Arbeitsplatz-Konzentration) under Deutsche Forschungsgemeinschaft
TWA: Time Weighted Average
STEL: Short Term Exposure Limit
WHMIS: Workplace Hazardous Materials Information System
NOHSC: National Occupational Health and Safety Commission
Abbreviations:
Revision Date:December 15, 2010Date of Issue:

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