Safety Data Sheet

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Transcript

1. IDENTIFICATION
Product identifier
Product Code 1074U-00WHA
Product Name ENDURA-SHIELD II TNEMEC WHITE
Other means of identification
Common Name SERIES 1074UV PART A
Recommended use of the chemical and restrictions on use
Recommended Use industrial paint.
Uses advised against Consumer use, For professional use only. Not for residential use.
Details of the supplier of the safety data sheet
Emergency telephone number
Company Phone Number Tnemec Regulatory Dept: 816-474-3400
24 Hour Emergency Phone Number 800-535-5053 (Infotrac)
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label elements
EMERGENCY OVERVIEW
Precautionary Statements
Prevention
Do not handle until all safety precautions have been read and understood
Response
Get medical advice/attention if you feel unwell
Storage
Keep away from children
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
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Page 1 / 10
Manufacturer Address
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO
64120-1372
Distributor
Tnemec Company, Inc. 86 Boul, des Entreprises, Ste. 203
Boisbriand, Quebec Canada J7G 2T3
Safety Data Sheet
Issue Date 14-Jan-2016 Revision Date 13-Jul-2011 Revision Number 2
Odor No information availableAppearance No information available Physical state No information available
______________________________________________________________________________________________
Other information
3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS-No Weight-%
NON-HAZARDOUS MATERIAL C323 1 - 10%
BIS (PENTAMETHYLPIPERIDYL) SEBACATE 41556-26-7 0.1 - 1%
XYLENE 1330-20-7 0.1 - 1%
PROPRIETARY 82919-37-7 0.1 - 1%
PROPYLENE GLYCOL MONOMETHYL ETHER
ACETATE
108-65-6 0 - 0.1%
PROPRIETARY B049 0 - 0.1%
CARBON BLACK DUST & FUME 1333-86-4 0 - 0.1%
TOLUENE 108-88-3 0 - 0.1%
WHITE SPIRITS - 0 - 0.1%
PROPYLENE GLYCOL MONOMETHYL ETHER
ACETATE
108-65-6 0 - 0.1%
PROPRIETARY - 0 - 0.1%
RED PIGMENT - 0 - 0.1%
SURFACTANT 68891-21-4 0 - 0.1%
KAOLIN 1332-58-7 0 - 0.1%
HYDROSULFURIZED PETROLEUM DISTILLATE,
MIDDLE
64742-80-9 0 - 0.1%
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice If symptoms persist, call a physician.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes.
Skin contact Wash off immediately with soap and plenty of water.
Inhalation Remove to fresh air. Oxygen or artificial respiration if needed.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing.
Most important symptoms and effects, both acute and delayed
Notes to physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media No information available.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe
fumes
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Revision Date 13-Jul-20111074U-00WHA ENDURA-SHIELD II TNEMEC WHITE
______________________________________________________________________________________________
Protective equipment and precautions for firefighters
Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from
heat/sparks/open flames/hot surfaces. MAY CAUSE HEAT AND PRESSURE BUILD-UP IN CLOSED CONTAINERS. Solvent
vapors are heavier than air and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with eyes, skin and clothing. Use personal protective equipment. Remove all
sources of ignition.
Environmental Precautions
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or
sanitary sewer system.
Methods and material for containment and cleaning up
Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for
proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate
ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer
absorbent material to suitable containers for proper disposal.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated
absorbent, container and unused contents in accordance with local, state and federal
regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling Close container after each use. Avoid contact with eyes, skin and clothing. Do not eat, drink
or smoke when using this product. If splashes are likely to occur, wear goggles. Wear
protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum. When
used in a mixture, read the labels and safety data sheets of all components. Wash
thoroughly after handling.
Conditions for safe storage, including any incompatibilities
Storage Keep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in
an area containing flame proof equipment. Extinguish all flames and pilot lights, and turn off
stoves, heaters, electric motors and other sources of ignition during use and until all vapors
are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross
ventilation.
Incompatible products No information available.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure guidelines .
Component ACGIH TLV OSHA PEL NIOSH IDLH
XYLENE
1330-20-7
TWA: 100 ppm
STEL: 150 ppm
TWA: 100 ppm
TWA: 435 mg/m3
STEL: 150 ppm
STEL: 655 mg/m3
CARBON BLACK DUST & FUME
1333-86-4
TWA: 3 mg/m3 TWA: 3.5 mg/m3 1750 mg/m3
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Revision Date 13-Jul-20111074U-00WHA ENDURA-SHIELD II TNEMEC WHITE
______________________________________________________________________________________________
TOLUENE
108-88-3
TWA: 20 ppm TWA: 100 ppm
TWA: 375 mg/m3
STEL: 150 ppm
STEL: 560 mg/m3
TWA: 200 ppm
Ceiling: 300 ppm
500 ppm
WHITE SPIRITS TWA: 100 ppm TWA: 100 ppm
TWA: 525 mg/m3
TWA: 500 ppm
TWA: 2900 mg/m3
20000 mg/m3
KAOLIN
1332-58-7
TWA: 2 mg/m3 TWA: 10 mg/m3
TWA: 5 mg/m3
TWA: 15 mg/m3
Appropriate engineering controls
Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and
general exhaust to keep the air contaminant concentration below current applicable OSHA
Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV).
Appropriate ventilation should be employed to remove hazardous decomposition products
formed during welding or flame cutting operations of surfaces coated with this product.
Individual protection measures, such as personal protective equipment
Eye/face protection If splashes are likely to occur, wear Goggles
Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls,
as appropriate, to prevent skin contact.
Respiratory protection Use only with adequate ventilation. Do not breathe vapors, spray mist, or dust. Ensure fresh
air entry during application and drying. If you experience eye watering, headache or
dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable
limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and
after application. Follow respirator manufacturer's directions for respirator use.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state No information available
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1074U-00WHA ENDURA-SHIELD II TNEMEC WHITE
No data available
Property
Flammability (solid, gas)
Values
Odor
Flammability Limit in Air
Remarks
No data available
No information available
Upper flammability limit N/A
pH Lower flammability limit 1.0
Revision Date 13-Jul-2011
Vapor pressure
No data available
No data available
Color
Vapor density
Melting point / freezing point
No data available
Specific gravity 1.34150
No information available
g/cm3
Literary Reference
Water solubility Insoluble in cold water
Solubility in other solvents
Boiling point / boiling range 118 °C / 244.0 °F
No data available
Partition coefficient: n-octanol/water
Odor threshold
No data available
No information available
Autoignition temperature
No information available
No data available
Flash point 37 °C / 98.0 °F
Appearance
Pensky Martens - Closed Cup
No information available
Evaporation rate
______________________________________________________________________________________________
Other Information
Density 11.16329 lbs/gal
Volatile organic compounds (VOC)
content
2.658 lbs/gal
Total volatiles weight percent 23.8130 %
Total volatiles volume percent 36.8728 %
10. STABILITY AND REACTIVITY
Reactivity
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
None under normal processing.
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
No information available
Hazardous decomposition products
Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke).
Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide. Hydrocarbons.
11. TOXICOLOGICAL INFORMATION
Information on Likely Routes of Exposure
Inhalation May cause central nervous system depression with nausea, headache, dizziness, vomiting,
and incoordination.
Eye contact Irritating to eyes.
Skin contact Irritating to skin.
Ingestion Harmful if swallowed.
Component LD50 Oral LD50 Dermal LC50 Inhalation
BIS (PENTAMETHYLPIPERIDYL)
SEBACATE
41556-26-7
= 2615 mg/kg ( Rat )
XYLENE
1330-20-7
= 3500 mg/kg ( Rat ) > 1700 mg/kg ( Rabbit ) > 4350
mg/kg ( Rabbit )
= 5000 ppm ( Rat ) 4 h = 29.08
mg/L ( Rat ) 4 h
PROPYLENE GLYCOL
MONOMETHYL ETHER ACETATE
108-65-6
= 8532 mg/kg ( Rat ) > 5 g/kg ( Rabbit )
CARBON BLACK DUST & FUME
1333-86-4
> 15400 mg/kg ( Rat ) > 3 g/kg ( Rabbit )
TOLUENE
108-88-3
= 2600 mg/kg ( Rat ) = 12000 mg/kg ( Rabbit ) = 12.5 mg/L ( Rat ) 4 h
PROPYLENE GLYCOL
MONOMETHYL ETHER ACETATE
108-65-6
= 8532 mg/kg ( Rat ) > 5 g/kg ( Rabbit )
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Revision Date 13-Jul-2011
Kinematic viscosity
No data available
1074U-00WHA ENDURA-SHIELD II TNEMEC WHITE
Decomposition temperature
Dynamic viscosity No data available
______________________________________________________________________________________________
HYDROSULFURIZED
PETROLEUM DISTILLATE,
MIDDLE
64742-80-9
> 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 4600 mg/m3 ( Rat ) 4 h
Information on toxicological effects
Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Skin disorders.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Chronic Toxicity Cancer hazard. Contains crystalline silica which can cause cancer. (Risk of cancer depends
on duration and level of exposure).
Sensitization No information available.
Mutagenicity No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component ACGIH IARC NTP OSHA
XYLENE
1330-20-7
Group 3
CARBON BLACK DUST &
FUME
1333-86-4
A3 Group 2B X
TOLUENE
108-88-3
Group 3
Reproductive effects No information available.
STOT - single exposure No information available
STOT - repeated exposure No information available
Target organ effects Central nervous system, Eyes, Lungs, Peripheral Nervous System (PNS), respiratory
system, Skin, blood, Gastrointestinal tract, kidney, liver.
Aspiration hazard Based on product level data, this product does not meet the requirement to be classified as
an aspiration hazard. However, this product contains an ingredient that may cause
aspiration if swallowed.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Component Toxicity to algae Toxicity to fish Toxicity to daphnia
BIS (PENTAMETHYLPIPERIDYL)
SEBACATE
41556-26-7
0.97: 96 h Lepomis macrochirus
mg/L LC50 static
20: 24 h Daphnia magna mg/L
EC50
XYLENE
1330-20-7
LC50= 13.4 mg/L Pimephales
promelas 96 h LC50 2.661 - 4.093
mg/L Oncorhynchus mykiss 96 h
LC50 13.5 - 17.3 mg/L
Oncorhynchus mykiss 96 h LC50
13.1 - 16.5 mg/L Lepomis
macrochirus 96 h LC50= 19 mg/L
Lepomis macrochirus 96 h LC50
7.711 - 9.591 mg/L Lepomis
macrochirus 96 h LC50 23.53 29.97 mg/L Pimephales promelas
96 h LC50= 780 mg/L Cyprinus
carpio 96 h LC50> 780 mg/L
Cyprinus carpio 96 h LC50 30.26 40.75 mg/L Poecilia reticulata 96 h
EC50 = 3.82 mg/L 48 h LC50 = 0.6
mg/L 48 h
PROPYLENE GLYCOL
MONOMETHYL ETHER ACETATE
108-65-6
161: 96 h Pimephales promelas
mg/L LC50 static
500: 48 h Daphnia magna mg/L
EC50
CARBON BLACK DUST & FUME
1333-86-4
5600: 24 h Daphnia magna mg/L
EC50
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Revision Date 13-Jul-20111074U-00WHA ENDURA-SHIELD II TNEMEC WHITE
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TOLUENE
108-88-3
433: 96 h Pseudokirchneriella
subcapitata mg/L EC50 12.5: 72 h
Pseudokirchneriella subcapitata
mg/L EC50 static
15.22 - 19.05: 96 h Pimephales
promelas mg/L LC50 flow-through
12.6: 96 h Pimephales promelas
mg/L LC50 static 5.89 - 7.81: 96 h
Oncorhynchus mykiss mg/L LC50
flow-through 14.1 - 17.16: 96 h
Oncorhynchus mykiss mg/L LC50
static 5.8: 96 h Oncorhynchus
mykiss mg/L LC50 semi-static 11.0 15.0: 96 h Lepomis macrochirus
mg/L LC50 static 54: 96 h Oryzias
latipes mg/L LC50 static 28.2: 96 h
Poecilia reticulata mg/L LC50
semi-static 50.87 - 70.34: 96 h
Poecilia reticulata mg/L LC50 static
5.46 - 9.83: 48 h Daphnia magna
mg/L EC50 Static 11.5: 48 h
Daphnia magna mg/L EC50
PROPYLENE GLYCOL
MONOMETHYL ETHER ACETATE
108-65-6
161: 96 h Pimephales promelas
mg/L LC50 static
500: 48 h Daphnia magna mg/L
EC50
HYDROSULFURIZED
PETROLEUM DISTILLATE,
MIDDLE
64742-80-9
35: 96 h Pimephales promelas mg/L
LC50 flow-through
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility in Environmental Media
Component log Pow
BIS (PENTAMETHYLPIPERIDYL) SEBACATE
41556-26-7
0.37
XYLENE
1330-20-7
2.77
PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE
108-65-6
0.43
TOLUENE
108-88-3
2.65
WHITE SPIRITS 3.16
PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE
108-65-6
0.43
Other Adverse Effects No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container and unused contents in
accordance with local, state and federal regulations.
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Component RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
XYLENE
1330-20-7
Included in waste stream:
F039
U239
TOLUENE
108-88-3
U220 Included in waste streams:
F005, F024, F025, F039,
K015, K036, K037, K149,
K151
U220
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Revision Date 13-Jul-20111074U-00WHA ENDURA-SHIELD II TNEMEC WHITE
______________________________________________________________________________________________
Component RCRA - Halogenated
Organic Compounds
RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes
TOLUENE
108-88-3
Toxic waste
waste number F025
Waste description:
Condensed light ends, spent
filters and filter aids, and
spent desiccant wastes from
the production of certain
chlorinated aliphatic
hydrocarbons, by free
radical catalyzed processes.
These chlorinated aliphatic
hydrocarbons are those
having carbon chain lengths
ranging from one to and
including five, with varying
amounts and positions of
chlorine substitution.
Component CAWAST
XYLENE
1330-20-7
Toxic
Ignitable
TOLUENE
108-88-3
Toxic
Ignitable
14. TRANSPORT INFORMATION
DOT
IATA
Additional information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes
of Transportation.
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Does not comply
ENCS Does not comply
IECSC Complies
KECL Does not comply
PICCS Does not comply
AICS Complies
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
Component HAPS Data
XYLENE
TOLUENE
United States of America
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1074U-00WHA ENDURA-SHIELD II TNEMEC WHITE Revision Date 13-Jul-2011
______________________________________________________________________________________________
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part
372:
Component SARA 313 - Threshold Values
XYLENE - 1330-20-7 1.0
TOLUENE - 108-88-3 1.0
SARA 311/312 Hazardous
Categorization
Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
Component CWA - Reportable
Quantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
XYLENE
1330-20-7
100 lb X
TOLUENE
108-88-3
1000 lb X X X
CERCLA
Component Hazardous Substances RQs CERCLA EHS RQs RQ
XYLENE
1330-20-7
100 lb RQ 100 lb final RQ
RQ 45.4 kg final RQ
TOLUENE
108-88-3
1000 lb 1 lb RQ 1000 lb final RQ
RQ 454 kg final RQ RQ 1 lb final
RQ
RQ 0.454 kg final RQ
United States of America
California Prop. 65
WARNING! This product contains a chemical known in the State of California to cause cancer
Component California Prop. 65
CARBON BLACK DUST & FUME - 1333-86-4 Carcinogen
TOLUENE - 108-88-3 Developmental
California SCAQMD Rule 443
Contains Photochemically Reactive Solvent
State Right-to-Know
Component New Jersey Massachusetts Pennsylvania
XYLENE
1330-20-7
X X X
CARBON BLACK DUST & FUME
1333-86-4
X X X
TOLUENE
108-88-3
X X X
WHITE SPIRITS X X X
KAOLIN
1332-58-7
X X X
16. OTHER INFORMATION
______________________________________________________________________________________________
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1074U-00WHA ENDURA-SHIELD II TNEMEC WHITE
HMIS (Hazardous
Material Information
System)
NFPA
Health 3* Flammability 3
Revision Date 13-Jul-2011
Reactivity 1
Health 0 Flammability 0 Instability 0 Physical hazard ______________________________________________________________________________________________
Prepared By Tnemec Regulatory Dept: 816-474-3400
Revision Date 13-Jul-2011
Revision Summary
No information available
Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or
any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained
herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards which exist.
End of SDS
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1074U-00WHA ENDURA-SHIELD II TNEMEC WHITE Revision Date 13-Jul-2011
1. IDENTIFICATION
Product identifier
Product Code 1074-1075B
Product Name ENDURA-SHIELD II CONVERTER
Other means of identification
Common Name SERIES 1074/1074U/1075/1075U, PART B
Recommended use of the chemical and restrictions on use
Recommended Use industrial paint.
Uses advised against Consumer use, For professional use only. Not for residential use.
Details of the supplier of the safety data sheet
Emergency telephone number
Company Phone Number Tnemec Regulatory Dept: 816-474-3400
24 Hour Emergency Phone Number 800-535-5053 (Infotrac)
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Inhalation (Vapors) Category 4
Respiratory sensitization Category 1
Skin sensitization Category 1
Specific target organ toxicity (single exposure) Category 3
Specific target organ toxicity (repeated exposure) Category 2
Label elements
EMERGENCY OVERVIEW
______________________________________________________________________________________________
Page 1 / 9
Danger
Flammable Liquids
Hazard statements
Harmful if inhaled
May cause allergy or asthma symptoms or breathing difficulties if inhaled
May cause an allergic skin reaction
May cause respiratory irritation. May cause drowsiness or dizziness
May cause damage to organs through prolonged or repeated exposure
Category 3
Revision Date 22-Jun-2015
Flammable liquid and vapor
Revision Number 12
Manufacturer Address
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
Safety Data Sheet
Issue Date 22-Jun-2015
______________________________________________________________________________________________
Precautionary Statements
Prevention
Use only outdoors or in a well-ventilated area
In case of inadequate ventilation wear respiratory protection
Contaminated work clothing should not be allowed out of the workplace
Do not breathe dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. — No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/mixing/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/protective clothing/eye protection/face protection
Keep cool
Response
Get medical advice/attention if you feel unwell
If skin irritation or rash occurs: Get medical advice/attention
Wash contaminated clothing before reuse
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician
In case of fire: Use CO2, dry chemical, or foam for extinction
Storage
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Keep away from children
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Other information
Toxic to aquatic life with long lasting effects
Acute Toxicity 89.8 % of the mixture consists of ingredient(s) of unknown toxicity.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS-No Weight-%
HEXAMETHYLENE DIISOCYANATE (HDI)
POLYMER
28182-81-2 60 - 100%
PETROLEUM SOLVENT (NAPHTHA) 64742-95-6 1 - 10%
1,2,4-TRIMETHYLBENZENE 95-63-6 1 - 10%
N-BUTYL ACETATE 123-86-4 1 - 10%
HEXAMETHYLENE DIISOCYANATE (HDI)
MONOMER
822-06-0 0.1 - 1%
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1074-1075B ENDURA-SHIELD II CONVERTER Revision Date 22-Jun-2015
Odor SlightAppearance opaque Physical state liquid
______________________________________________________________________________________________
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice If symptoms persist, call a physician.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes. If eye irritation persists,
consult a specialist.
Skin contact Wash off immediately with soap and plenty of water. If symptoms persist, call a physician.
Inhalation Remove to fresh air. Oxygen or artificial respiration if needed. If inhaled, remove to fresh
air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention immediately.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing.
Most important symptoms and effects, both acute and delayed
Notes to physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide. Foam. Dry chemical.
Unsuitable extinguishing media Water.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe
fumes
Hazardous combustion productsHazardous combustion products may include: A complex mixture of airborne solid and
liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic
compounds. Carbon oxides. Hydrocarbons. Oxides of nitrogen. Hydrogen cyanide.
Protective equipment and precautions for firefighters
Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from
heat/sparks/open flames/hot surfaces. MAY CAUSE HEAT AND PRESSURE BUILD-UP IN CLOSED CONTAINERS. Solvent
vapors are heavier than air and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with eyes, skin and clothing. Use personal protective equipment. Remove all
sources of ignition.
Environmental Precautions
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or
sanitary sewer system.
Methods and material for containment and cleaning up
______________________________________________________________________________________________
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1074-1075B ENDURA-SHIELD II CONVERTER Revision Date 22-Jun-2015
______________________________________________________________________________________________
Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for
proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate
ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer
absorbent material to suitable containers for proper disposal.
Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated
absorbent, container and unused contents in accordance with local, state and federal
regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling Wear personal protective equipment. Avoid contact with eyes, skin and clothing. Handle in
accordance with good industrial hygiene and safety practice. Remove and wash
contaminated clothing before re-use. Do not eat, drink or smoke when using this product.
Close container after each use. When used in a mixture, read the labels and safety data
sheets of all components. Wash thoroughly after handling.
Conditions for safe storage, including any incompatibilities
Storage Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of
children.
Incompatible products Strong oxidizing agents. caustic. Water, alcohols, amines, strong bases, metal components,
surface active materials.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure guidelines .
Component ACGIH TLV OSHA PEL NIOSH IDLH
N-BUTYL ACETATE
123-86-4
TWA: 150 ppm
STEL: 200 ppm
TWA: 150 ppm
TWA: 710 mg/m3
STEL: 200 ppm
STEL: 950 mg/m3
1700 ppm
HEXAMETHYLENE
DIISOCYANATE (HDI) MONOMER
822-06-0
TWA: 0.005 ppm NIOSH IDLH: Immediately Dangerous to Life or Health
Appropriate engineering controls
Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and
general exhaust to keep the air contaminant concentration below current applicable OSHA
Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV).
Appropriate ventilation should be employed to remove hazardous decomposition products
formed during welding or flame cutting operations of surfaces coated with this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Safety glasses with side-shields If splashes are likely to occur, wear face-shield.
Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls,
as appropriate, to prevent skin contact.
______________________________________________________________________________________________
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1074-1075B ENDURA-SHIELD II CONVERTER Revision Date 22-Jun-2015
______________________________________________________________________________________________
Respiratory protection INDIVIDUALS WITH LUNG OR BREATHING PROBLEMS OR PRIOR REACTION TO
ISOCYANATES MUST NOT BE EXPOSED TO VAPOR OR SPRAY MIST. Do not breathe
vapor or spray mist. Wear an appropriate, properly fitted respirator (NIOSH/MSHA
approved) during and after application unless air monitoring demonstrates vapor/mist levels
are below applicable limits. An airline respirator (TC 19C NIOSH/MSHA) is recommended.
A vapor-particulate respirator (TC 23C NIOSH/MSHA) may be appropriate where air
monitoring demonstrates vapors are less than ten times the applicable exposure limits and
the isocyanate concentration is less than its applicable exposure limit. The use of an
air-supplied respirator is mandatory whenever the airborne concentration of isocyanate
monomer is unknown.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state liquid
Other Information
Density 9.34946 lbs/gal
Volatile organic compounds (VOC)
content
0.93495 lbs/gal
Total volatiles weight percent 10 %
Total volatiles volume percent 13.9 %
10. STABILITY AND REACTIVITY
Reactivity
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
None under normal processing.
______________________________________________________________________________________________
Page 5 / 9
Color
Vapor density
Melting point / freezing point
No data available
Specific gravity 1.12104
No information available
g/cm3
No data available
Water solubility Insoluble in cold water
Solubility in other solvents
Boiling point / boiling range 72 °C / 162 °F
No data available
Partition coefficient: n-octanol/water
Odor threshold
No data available
Autoignition temperature
No information available
No data available
Flash point
Decomposition temperature
38 °C / 100.4 °F
No data available
Appearance
Kinematic viscosity
Pensky Martens - Closed Cup
No data available
opaque
Dynamic viscosity 875 centipoises approx
Evaporation rate
1074-1075B ENDURA-SHIELD II CONVERTER
No data available
Property
Flammability (solid, gas)
Values
Not applicable
Odor
Flammability Limit in Air
Remarks
No data available
Slight
Upper flammability limit N/A
No data available
pH Lower flammability limit N/A
Revision Date 22-Jun-2015
Vapor pressure
No data available
No data available
______________________________________________________________________________________________
Conditions to avoid
Heat, flames and sparks. Keep away from children. Amines.
Incompatible materials
Strong oxidizing agents, caustic, Water, alcohols, amines, strong bases, metal components, surface active materials
Hazardous decomposition products
Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke).
Carbon monoxide. Unidentified organic and inorganic compounds. Carbon oxides. Nitrogen oxides (NOx). Hydrocarbons.
Hydrogen cyanide.
11. TOXICOLOGICAL INFORMATION
Information on Likely Routes of Exposure
Inhalation Contains isocyanate monomer. If subject to spray application, engineering and
administrative controls must be instituted to maintain an exposure level below .005ppm. If
these controls are not adequate, the use of an air-supplied respirator is mandatory.
Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness,
cessation of breathing. May cause sensitization of susceptible persons.
Eye contact Causes serious eye irritation.
Skin contact May cause sensitization of susceptible persons. Irritating to skin.
Ingestion Harmful if swallowed.
Component LD50 Oral LD50 Dermal LC50 Inhalation
HEXAMETHYLENE
DIISOCYANATE (HDI) POLYMER
28182-81-2
= 18500 mg/m3 ( Rat ) 1 h
PETROLEUM SOLVENT
(NAPHTHA)
64742-95-6
= 8400 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 3400 ppm ( Rat ) 4 h
1,2,4-TRIMETHYLBENZENE
95-63-6
= 3280 mg/kg ( Rat ) > 3160 mg/kg ( Rabbit ) = 18 g/m3 ( Rat ) 4 h
N-BUTYL ACETATE
123-86-4
= 10768 mg/kg ( Rat ) = 14.13
mg/kg ( Rat )
> 17600 mg/kg ( Rabbit ) = 390 ppm ( Rat ) 4 h
HEXAMETHYLENE
DIISOCYANATE (HDI) MONOMER
822-06-0
= 738 mg/kg ( Rat ) = 593 mg/kg ( Rabbit ) = 0.06 mg/L ( Rat ) 4 h
Information on toxicological effects
Symptoms Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness,
cessation of breathing. Skin disorders. Respiratory disorders. Irritating to eyes and skin.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Chronic Toxicity Avoid repeated exposure. Contains isocyanates. May produce an allergic reaction.
Sensitization May cause sensitization of susceptible persons.
Mutagenicity May cause genetic defects.
Carcinogenicity There are no known carcinogenic chemicals in this product.
Reproductive effects No information available.
STOT - single exposure Respiratory system, Skin
STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure
Target organ effects Central nervous system, Eyes, respiratory system, Skin, blood.
Aspiration hazard Not applicable.
Acute Toxicity 89.8 % of the mixture consists of ingredient(s) of unknown toxicity.
12. ECOLOGICAL INFORMATION
______________________________________________________________________________________________
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1074-1075B ENDURA-SHIELD II CONVERTER Revision Date 22-Jun-2015
______________________________________________________________________________________________
Ecotoxicity
Toxic to aquatic life with long lasting effects
98.801 % of the mixture consists of components(s) of unknown hazards to the aquatic environment
Component Toxicity to algae Toxicity to fish Toxicity to daphnia
PETROLEUM SOLVENT
(NAPHTHA)
64742-95-6
9.22: 96 h Oncorhynchus mykiss
mg/L LC50
6.14: 48 h Daphnia magna mg/L
EC50
1,2,4-TRIMETHYLBENZENE
95-63-6
7.19 - 8.28: 96 h Pimephales
promelas mg/L LC50 flow-through
6.14: 48 h Daphnia magna mg/L
EC50
N-BUTYL ACETATE
123-86-4
674.7: 72 h Desmodesmus
subspicatus mg/L EC50
62: 96 h Leuciscus idus mg/L LC50
static 100: 96 h Lepomis
macrochirus mg/L LC50 static 17 19: 96 h Pimephales promelas mg/L
LC50 flow-through
72.8: 24 h Daphnia magna mg/L
EC50
HEXAMETHYLENE
DIISOCYANATE (HDI) MONOMER
822-06-0
26.1: 96 h Brachydanio rerio mg/L
LC50 static
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility in Environmental Media
Component log Pow
1,2,4-TRIMETHYLBENZENE
95-63-6
3.63
N-BUTYL ACETATE
123-86-4
1.81
Other Adverse Effects No information available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container and unused contents in
accordance with local, state and federal regulations.
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or
disposal.
California Hazardous Waste Status
This product contains one or more substances that are listed with the State of California as a hazardous waste
Component CAWAST
N-BUTYL ACETATE
123-86-4
Toxic
14. TRANSPORT INFORMATION
DOT
Proper Shipping Name paint in oil Not regulated
IATA
UN/ID no. 1263
______________________________________________________________________________________________
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1074-1075B ENDURA-SHIELD II CONVERTER Revision Date 22-Jun-2015
______________________________________________________________________________________________
Proper Shipping Name paint
Hazard Class 3
Packing Group III
ERG Code 366
Additional information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes
of Transportation.
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Does not comply
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
Component HAPS Data
HEXAMETHYLENE DIISOCYANATE (HDI) MONOMER
United States of America
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part
372:
Component SARA 313 - Threshold Values
1,2,4-TRIMETHYLBENZENE - 95-63-6 1.0
HEXAMETHYLENE DIISOCYANATE (HDI) MONOMER - 822-06-0 1.0
SARA 311/312 Hazardous
Categorization
Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
Component CWA - Reportable
Quantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
N-BUTYL ACETATE
123-86-4
5000 lb X
CERCLA
Component Hazardous Substances RQs CERCLA EHS RQs RQ
N-BUTYL ACETATE
123-86-4
5000 lb RQ 5000 lb final RQ
RQ 2270 kg final RQ
______________________________________________________________________________________________
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Revision Date 22-Jun-20151074-1075B ENDURA-SHIELD II CONVERTER
______________________________________________________________________________________________
HEXAMETHYLENE
DIISOCYANATE (HDI) MONOMER
822-06-0
100 lb RQ 100 lb final RQ
RQ 45.4 kg final RQ
United States of America
California Prop. 65
This product does not contain any Proposition 65 chemicals
California SCAQMD Rule 443
Contains Photochemically Reactive Solvent
State Right-to-Know
Component New Jersey Massachusetts Pennsylvania
1,2,4-TRIMETHYLBENZENE
95-63-6
X X X
N-BUTYL ACETATE
123-86-4
X X X
HEXAMETHYLENE
DIISOCYANATE (HDI) MONOMER
822-06-0
X X
16. OTHER INFORMATION
Prepared By Tnemec Regulatory Dept: 816-474-3400
Revision Date 22-Jun-2015
Revision Summary
9 4 5 7 10 8 11 2 14 15
Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or
any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained
herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards which exist.
End of MSDS
______________________________________________________________________________________________
Page 9 / 9
1074-1075B ENDURA-SHIELD II CONVERTER
Instability 1 Physical hazard *
Revision Date 22-Jun-2015
HMIS (Hazardous
Material Information
System)
NFPA
Health 2* Flammability 2 Reactivity 1
Health 2 Flammability 2

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