MAZDA ORIGINAL OIL ULTRA DPF 5W-30

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Classification, ORIGINAL, ULTRA, MAZDA, Version, 5W-30, Hopital, uses, with, ____________________________________________________________________________________________, (0)1, amendments, IDENTIFICATION, Product, 2.2., Date:, Section, Quick-FDS, Section,, this, mentioned, text, full, substance, mixture, [16529-49394-16552-018641], France, Mixture, cedex, substance/mixture

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Quick-FDS [16529-49394-16552-018641] - 2013-04-02 - 13:43:15
____________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
MAZDA ORIGINAL OIL ULTRA
DPF 5W-30
Page 1 / 13
SDS # : 081070
Pure substance/mixture
1.3. Details of the supplier of the safety data sheet
+33 1 49 00 00 49 (24h/24, 7d/7)
Mixture
France - ORFILA (INRS) Tél : +33 (0)1 45 42 59 59
In France : - PARIS : Hôpital Fernand Widal 200, rue du Faubourg Saint-Denis 75475 Paris Cédex 10 , Tel : 01.40.05.48.48. MARSEILLE : Hopital Salvator, 249 bd Ste Marguerite 13274 Marseille cedex 5, Tel : 04.91.75.25.25. - LYON : Hopital Edouard
Herriot, 5 place d'Arsonvol, 69437 Lyon cedex 3, Tel : 04.72.11.69.11. - NANCY : Hopital central, 29 Av du Mal De Lattre de
Tassigny, 54000 Nancy, Tel : 03.83.32.36.36 ou le SAMU : Tel ( 15 )
Supplier TOTAL LUBRIFIANTS
562 Avenue du Parc de L'ile
92029 Nanterre Cedex
Tél: +33 (0)1 41 35 40 00
Fax: +33 (0)1 41 35 84 71
2. HAZARDS IDENTIFICATION
Product name
1.2. Relevant identified uses of the substance or mixture and uses advised against
2.1. Classification of the substance or mixture
For further information, please contact:
MAZDA ORIGINAL OIL ULTRA DPF 5W-30
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
REGULATION (EC) No 1272/2008
1.1. Product identifier
For the full text of the H-Statements mentioned in this Section, see Section 2.2.
Contact Point HSE
Number
Identified uses
E-mail Address rm.msds-lubs@total.com
Motor oil.
7I7
1.4. Emergency telephone number
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MAZDA ORIGINAL OIL ULTRA
DPF 5W-30
Version 1.01
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SDS # : 081070
Classification
R52-53 ***
2.3. Other hazards
Hazard pictograms
none
For the full text of the R-phrases mentioned in this Section, see Section 16
2.2. Label elements
Physical-Chemical Properties Contaminated surfaces will be extremely slippery.
The substance/mixture is classified as dangerous in accordance with Directive(s) 67/548/EEC with amendments and/or
1999/45/EC with amendments
Environmental properties Should not be released into the environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixture
Labelled according to
Chemical Name EC-No REACH registration
No CAS-No Weight % Classification (Dir.
67/548)
Classification (Reg.
1272/2008)
R-phrase(s)
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment***
Phosphorodithioic acid, mixed
O,O-bis(1,3-dimethylbutyl and
iso-Pr) esters, zinc salts***
283-392-8*
**
01-2119493626-26 84605-29-8 <1.5 Xi;R38-41
N;R51-53
Aquatic Chronic 2 (H411)
Eye Dam. 1 (H318)
Skin Irrit. 2 (H315)
Directive 1999/45/EC
DIRECTIVE 67/548/EEC or 1999/45/EC
Phenol, dodecyl-, branched*** 310-154-3 01-2119513207-49 121158-58-5 <0.5 Xi;R36/38
N;R50-53
Repr.Cat.3;R62
Aquatic Acute 1 (H400)
Aquatic Chronic 1 (H410)
Eye Irrit. 2 (H319)
Repr. 2 (H361)
Skin Irrit. 2 (H315)
S-phrase(s)
S61 - Avoid release to the environment. Refer to special instructions/safety data sheets***
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DPF 5W-30
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For the full text of the H-Statements mentioned in this Section, see Section 16.
Eye contact Not classified.
no data available
Eye contact
Skin contact Not classified.
Rinse thoroughly with plenty of water, also under the eyelids.
122-39-4
Inhalation Not classified. Inhalation of vapors in high concentration may cause irritation of respiratory
system.
Additional information
4. FIRST AID MEASURES
Skin contact Remove contaminated clothing and shoes. Wash off with soap and water. Wash
contaminated clothing before reuse.
Ingestion Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhea.
Product containing mineral oil with less than 3% DMSO extract as measured by IP 346
<0.5
4.3. Indication of immediate medical attention and special treatment needed, if necessary
Inhalation Move to fresh air.
T; R23/24/25
R33
N; R50-53
***
Notes to physician Treat symptomatically.
4.1. Description of first-aid measures
Acute Tox. 3 (H301)
Acute Tox. 3 (H311)
Acute Tox. 3 (H331)
STOT RE 2 (H373)
Aquatic Acute 1 (H400)
Aquatic Chronic 1 (H410)***
5. FIRE-FIGHTING MEASURES
Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a
physician or Poison Control Center immediately.
Diphenylamine***
For the full text of the R-phrases mentioned in this Section, see Section 16
204-539-4*
**
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4.2. Most important symptoms and effects, both acute and delayed
General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR
EMERGENCY MEDICAL CARE.
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MAZDA ORIGINAL OIL ULTRA
DPF 5W-30
Version 1.01
Other information Cool containers / tanks with water spray. Fire residues and contaminated fire extinguishing
water must be disposed of in accordance with local regulations.
General Information Do not allow material to contaminate ground water system. Try to prevent the material from
entering drains or water courses. Local authorities should be advised if significant spillages
cannot be contained.
6.3. Methods and materials for containment and cleaning up
6. ACCIDENTAL RELEASE MEASURES
Suitable Extinguishing Media
5.3. Advice for fire-fighters
Methods for cleaning up Dam up. Contain spillage, and then collect with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according
to local / national regulations (see section 13). Keep in suitable, closed containers for
disposal.
5.2. Special hazards arising from the substance or mixture
Carbon dioxide (CO 2). ABC powder. Foam. Water spray or fog.
6.4. Reference to other sections
6.1. Personal precautions, protective equipment and emergency procedures
Unsuitable Extinguishing Media
Personal Protective Equipment See Section 8 for more detail.
Special protective equipment for
fire-fighters
General Information Do not touch or walk through spilled material. Contaminated surfaces will be extremely
slippery. Use personal protective equipment. Ensure adequate ventilation. Remove all
sources of ignition.
Waste treatment See section 13.
Wear self-contained breathing apparatus and protective suit.
Do not use a solid water stream as it may scatter and spread fire.
5.1. Extinguishing media
Version EU
6.2. Environmental precautions
Special Hazard Incomplete combustion and thermolysis may produce gases of varying toxicity such as
carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may
be highly dangerous if inhaled in confined spaces or at high concentration.
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MAZDA ORIGINAL OIL ULTRA
DPF 5W-30
Version 1.01
7.2. Conditions for safe storage, including any incompatibilities
Take precautionary measures against static discharges: Ground/bond containers, tanks
and transfer/receiving equipment.
8.1. Control parameters
7. HANDLING AND STORAGE
Technical measures/Storage
conditions
Exposure limits oil mist : 10mg/m3, for 15 minutes oil mist : 5mg/m3, for 8 hours
Keep away from food, drink and animal feedingstuffs. Keep in a bunded area. Keep
container tightly closed. Keep preferably in the original container. Otherwise reproduce all
indication of the regulation label on the new container. Do not remove the hazard labels of
the containers (even if they are empty). Design the installations in order to avoid accidental
emissions of product (due to seal breakage, for example) onto hot casings or electrical
contacts. Protect from frost, heat and sunlight. Protect from moisture.
Advice on safe handling When using, do not eat, drink or smoke. For personal protection see section 8. Use only in
well-ventilated areas. Do not breathe vapors or spray mist. Avoid contact with skin, eyes
and clothing.
Legend See section 16
Hygiene measures Ensure the application of strict rules of hygiene by the personnel exposed to the risk of
contact with the product. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product. Do
not use abrasives, solvents or fuels. Do not dry hands with rags that have been
contaminated with product. Do not put product contaminated rags into workwear pockets.
Materials to Avoid Strong oxidizing agents.
7.1. Precautions for safe handling
DNEL Worker (Industrial/Professional)***
Chemical Name Short term, systemic
effects
Short term, local effects Long term, systemic
effects
Long term, local effects
7.3. Specific end uses
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Prevention of fire and explosion
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DPF 5W-30
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SDS # : 081070
Occupational Exposure Controls
0.075 mg/kg bw/day
Dermal
0.79 mg/m³ Inhalation
0.075 mg/kg bw/day
Oral***
Engineering Measures Apply technical measures to comply with the occupational exposure limits. When working in
confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for
breathing and wear the recommended equipment.
166 mg/kg bw/day
Dermal
44.18 mg/m³ Inhalation***
DNEL Consumer***
Predicted No Effect Concentration
(PNEC)
***
Personal Protective Equipment
0.25 mg/kg bw/day
Dermal
1.7621 mg/m³
Inhalation***
General Information If the product is used in mixtures, it is recommended that you contact the appropriate
protective equipment suppliers. These recommendations apply to the product as supplied.
Chemical Name Short term, systemic
effects
Chemical Name
Respiratory protection When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators. Respirator with combination filter for vapour/particulate (EN
14387). The use of breathing apparatus must comply strictly with the manufacturer's
instructions and the regulations governing their choices and uses.
Water Sediment Soil Air
Eye Protection If splashes are likely to occur, wear:. Safety glasses with side-shields.
STP Oral
Short term, local effects Long term, systemic
effects
Skin and body protection Wear suitable protective clothing. Protective shoes or boots. Long sleeved clothing.
Phenol, dodecyl-,
branched***
121158-58-5
0.074 µg/l fw
0.0074 µg/l mw
0.37 µg/l or***
0.226 mg/kg fw
dw 0.0266 mg/kg mw
dw***
0.118 mg/kg
dw***
Hand Protection Hydrocarbon-proof gloves. Fluorinated rubber. Nitrile rubber. Please observe the
instructions regarding permeability and breakthrough time which are provided by the
supplier of the gloves. Also take into consideration the specific local conditions under which
the product is used, such as the danger of cuts, abrasion. If used in solution, or mixed with
other substances, and under conditions which differ from EN 374, contact the supplier of
the EC approved gloves.
100 mg/l*** 4 mg/kg food***
Long term, local effects
8.2. Exposure controls
Phenol, dodecyl-,
branched***
121158-58-5
Version EU
Phenol, dodecyl-,
branched***
121158-58-5
50 mg/kg bw/day Dermal
13.26 mg/m³ Inhalation
1.26 mg/kg bw/day
Oral***
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DPF 5W-30
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SDS # : 081070
The product should not be allowed to enter drains, water courses or the soil.
Color brown
Environmental exposure controls
Physical State @20°C liquid
Odor Characteristic
9.2. Other information
9.1. Information on basic physical and chemical properties
10. STABILITY AND REACTIVITY
10.1. Reactivity
10.2. Chemical stability
Stability Stable under recommended storage conditions.
General Information
9. PHYSICAL AND CHEMICAL PROPERTIES
@ 100 °C
Method
No information available
ISO 3104
ASTM D 92
Autoignition temperature
Water solubility
Explosive properties Not explosive
> 250 °C
Oxidizing Properties Not applicable
Vapor density
Possibility of hazardous reactions Not applicable
Insoluble
ASTM E 659-78
No information available
pH Flash point
Values
> 482 °F
Solubility in other solvents
442 °F
No information available
Property
No information available
ASTM E 659-78
Flammability Limits in Air No information available
Soluble in many common
organic solvents
Viscosity, kinematic
228 °C
Density
Not applicable
Boiling point/boiling range
Vapor Pressure
logPow
ASTM D 92.
854 kg/m3
Remarks
@ 15 °C
No information available
Version EU
10.4 - 11 mm2/s
Evaporation rate
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DPF 5W-30
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SDS # : 081070
Materials to Avoid
Inhalation . Not classified. Inhalation of vapors in high concentration may cause irritation of
respiratory system.
Strong oxidizing agents.
Heat (temperatures above flash point), sparks, ignition points, flames, static electricity.
Ingestion . Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhea.
None under normal processing.
11.1. Information on toxicological effects
10.4. Conditions to Avoid
Acute toxicity - Component Information
10.6. Hazardous Decomposition Products
Acute toxicity Local effects Product Information
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
10.3. Possibility of hazardous reactions
Phosphorodithioic acid, mixed
O,O-bis(1,3-dimethylbutyl and iso-Pr)
esters, zinc salts***
= 2000 mg/kg ( Rat ) > 3200 mg/kg ( Rabbit )
Phenol, dodecyl-, branched*** LD50 2100 mg/kg (Rat-OECD
401) ***
LD50 15000 mg/kg
(Rabbit-OECD 402)***
10.5. Incompatible Materials
Diphenylamine*** = 1165 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit )
Sensitization
Hazardous Decomposition Products
Sensitization Not classified as a sensitizer.
Skin contact . Not classified.
None under normal use.
Specific effects
Eye contact . Not classified.
Version EU
Hazardous Reactions
Conditions to Avoid
11. TOXICOLOGICAL INFORMATION
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MAZDA ORIGINAL OIL ULTRA
DPF 5W-30
Version 1.01
No information available.
Other adverse effects Characteristic skin lesions (pimples) may develop following prolonged and repeated
exposures (contact with contaminated clothing).
Reproductive toxicity
Acute aquatic toxicity - Component Information
This product does not present any known or suspected reproductive hazards.
Chemical Name Toxicity to algae Toxicity to daphnia and
other aquatic invertebrates
Toxicity to fish Toxicity to
microorganisms
Target Organ Effects (STOT)
Phosphorodithioic acid,
mixed
O,O-bis(1,3-dimethylbutyl
and iso-Pr) esters, zinc
salts***
84605-29-8
EC50 (48h) 0.1 - 1 mg/L
Daphnia magna
LC50 (96h) 10-100 mg/L
Pimephales promelas
(static) LC50 (96h) > 100
mg/L Pimephales promelas
(semi-static)
12. ECOLOGICAL INFORMATION
Phenol, dodecyl-,
branched***
121158-58-5
EC50(72h) 0.26-0.50 mg/l
Desmodesmus subspicatus
static (OECD 201)***
EC50(48h) 0.037 mg/l
Daphnia magna static
(OECD 202)***
EL50(96h) 40 mg/l
Pimephales promelas
semi-static (OECD 203)***
Target Organ Effects (STOT)
Diphenylamine***
122-39-4
EC50 (72h) = 1.5 mg/l
Scenedesmus subspicatus
EC50 (48h) 1.69 - 2.46
mg/L Daphnia magna
LC50 (96h) 3.47-4.14 mg/L
Pimephales promelas
(flow-through)
EC50 = 4.77 mg/L 30 min
EC50 = 2.81 mg/L 5 min
EC50 = 3.46 mg/L 15 min
No information available.
Repeated Dose Toxicity
12.1. Toxicity
Chronic aquatic toxicity • Product Information
Mutagenicity
No information available.
This product is not classified as mutagenic.
Subchronic toxicity
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Chronic aquatic toxicity - Component Information
Other information
No information available.
Carcinogenicity
Version EU
Acute aquatic toxicity - Product Information
This product is not classified carcinogenic. During use in engines, contamination of oil with
low levels of combustion products occurs. Used motor oils have been shown to cause skin
cancer in mice following repeated application and continuous exposure. Brief or intermittent
skin contact with used motor oil is not expected to have serious effects in humans if the oil
is thoroughly removed by washing with soap and water.
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.
Soil Given its physical and chemical characteristics, the product generally shows low soil
mobility.
Chemical Name
No information available.
12.3. Bioaccumulative potential
Air Loss by evaporation is limited.
Phenol, dodecyl-,
branched***
121158-58-5
Water Insoluble. The product spreads on the surface of the water.
Product Information No information available.
NOEC(21d) 0.0037 mg/l
Daphnia magna semi-static
(OECD 211)***
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment No information available.
logPow No information available
12.6. Other adverse effects
Toxicity to algae
Component Information .
12.2. Persistence and degradability
General Information No information available.
Toxicity to daphnia and
other aquatic invertebrates
Chemical Name log Pow
13. DISPOSAL CONSIDERATIONS
Phenol, dodecyl-, branched*** - 121158-58-5 7.1
13.1. Waste treatment methods
Toxicity to fish
Diphenylamine*** - 122-39-4 3.4***
General Information
No information available.
Toxicity to
microorganisms
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12.4. Mobility in soil
Effects on terrestrial organisms
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MAZDA ORIGINAL OIL ULTRA
DPF 5W-30
Version 1.01
Waste from Residues / Unused
Products
15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
IMDG/IMO Not regulated
14. TRANSPORT INFORMATION
European Union
Should not be released into the environment. Dispose of in accordance with the European
Directives on waste and hazardous waste. Dispose of in accordance with local regulations.
Where possible recycling is preferred to disposal or incineration. After use, this oil must be
sent to a licensed waste oil facility. Incorrect disposal of used oil poses a risk to the
environment. Mixture with other waste types such as solvents, brake- and cooling liquids is
forbidden.
International Inventories
ICAO/IATA
EINECS/ELINCS -
Not regulated
TSCA -
DSL -
EWC Waste Disposal No.
ENCS -
ADN
IECSC -
Not regulated
KECL -
The following Waste Codes are only suggestions:. 13 02 05. According to the European
Waste Catalogue, Waste Codes are not product specific, but application specific. Waste
codes should be assigned by the user based on the application for which the product was
used.
PICCS -
Contaminated packaging
ADR/RID Not regulated
Version EU
Empty containers should be taken to an approved waste handling site for recycling or
disposal.
15. REGULATORY INFORMATION
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DPF 5W-30
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AICS
16. OTHER INFORMATION
IECSC - China Inventory of Existing Chemical Substances
-
Further information
Full text of R-phrases referred to under sections 2 and 3
R41 - Risk of serious damage to eyes
R38 - Irritating to skin
R62 - Possible risk of impaired fertility
R33 - Danger of cumulative effects***
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R36/38 - Irritating to eyes and skin
R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment***
KECL - Korean Existing and Evaluated Chemical Substances
Legend
Full text of H-Statements referred to under sections 2 and 3
H301 - Toxic if swallowed
H311 - Toxic in contact with skin
H315 - Causes skin irritation
H318 - Causes serious eye damage
H319 - Causes serious eye irritation
H331 - Toxic if inhaled
H373 - May cause damage to organs through prolonged or repeated exposure
H361f - Suspected of damaging fertility
H400 - Very toxic to aquatic life
H410 - Very toxic to aquatic life with long lasting effects
H411 - Toxic to aquatic life with long lasting effects***
PICCS - Philippines Inventory of Chemicals and Chemical Substances
Abbreviations, acronyms
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
15.2. Chemical Safety Assessment
NZIoC
AICS - Australian Inventory of Chemical Substances
-
ENCS - Japan Existing and New Chemical Substances
Version EU
Chemical Safety Assessment No information available
NZIoC - New Zealand Inventory of Chemicals
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
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This safety data sheet serves to complete but not to replace the technical product sheets. The information contained
herein is given in good faith and is accurate to the best of knowledge at the date indicated above.It is understood by the
user that any use of the product for purposes other than those for which it was designed entails potential risk.The
information given herein in no way dispenses the user from knowing and applying all provisions regulating his
activity.The user bears sole liability for the precautions required when using the product.The regulatory texts indicated
herein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and exhaustive.It is
the user's responsibility to ensure that he is subject to no other obligations than those mentioned.
Revision Date: 2013-02-18
End of the safety data sheet
Legend Section 8
Revision Note *** Indicates updated section.
This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
____________________________________________________________________________________________
**
M: Mutagen
Hazard Designation
* Skin designation+
R: Toxic to reproduction
Version EU
Sensitizer
C: Carcinogen

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